Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis

Marhaini Mostapha, Noorhasmiera Abu Jahar, Siew Xian Chin, Sharifah Nabihah Syed Jaafar, Sarani Zakaria, Wan Mohd Aizat Wan Kamaruddin, Kamalrul Azlan Azizan

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

The effectiveness in the dehydration of sugars into 5-Hydroxymethylfurfural is related to the catalyst existence. A comprehensive synthesis of 5-Hydroxymethylfurfural from fructose, glucose and sucrose (3.73 mmol) with and without addition zeolite catalyst was performed in this study. The reactions were carried out in water-methanol solvent system for 3 hours reaction time at 180°C temperature. The catalytic results from HPLC showed that the reaction with zeolite increases the yield of 5-Hydroxymethylfurfural with 51.72 %, 34.01% and 50.10% for fructose, glucose and sucrose respectively. The study suggests that zeolites promote the isomerization of glucose into fructose to occur and simultaneously catalyze the dehydration of fructose into 5-Hydroxymethylfurfural. Only slight changes on FT-IR spectra of use zeolite after the reaction was observed. Thus suggest that zeolite was a potential catalyst for catalytic reaction for the conversion of sugar into 5-Hydroxymethylfurfural.

Original languageEnglish
Title of host publication2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium
PublisherAmerican Institute of Physics Inc.
Volume1784
ISBN (Electronic)9780735414464
DOIs
Publication statusPublished - 17 Nov 2016
Event2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016 - Selangor, Malaysia
Duration: 13 Apr 201614 Apr 2016

Other

Other2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016
CountryMalaysia
CitySelangor
Period13/4/1614/4/16

Fingerprint

sugars
dehydration
glucose
catalysts
sucrose
synthesis
reaction time
zeolites
isomerization
methyl alcohol
water
temperature

Keywords

  • Fructose
  • glucose
  • HPLC
  • solid catalyst
  • sucrose

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Mostapha, M., Jahar, N. A., Chin, S. X., Syed Jaafar, S. N., Zakaria, S., Wan Kamaruddin, W. M. A., & Azizan, K. A. (2016). Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis. In 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium (Vol. 1784). [040026] American Institute of Physics Inc.. https://doi.org/10.1063/1.4966812

Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis. / Mostapha, Marhaini; Jahar, Noorhasmiera Abu; Chin, Siew Xian; Syed Jaafar, Sharifah Nabihah; Zakaria, Sarani; Wan Kamaruddin, Wan Mohd Aizat; Azizan, Kamalrul Azlan.

2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784 American Institute of Physics Inc., 2016. 040026.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Mostapha, M, Jahar, NA, Chin, SX, Syed Jaafar, SN, Zakaria, S, Wan Kamaruddin, WMA & Azizan, KA 2016, Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis. in 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. vol. 1784, 040026, American Institute of Physics Inc., 2016 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2016, Selangor, Malaysia, 13/4/16. https://doi.org/10.1063/1.4966812
Mostapha M, Jahar NA, Chin SX, Syed Jaafar SN, Zakaria S, Wan Kamaruddin WMA et al. Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis. In 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784. American Institute of Physics Inc. 2016. 040026 https://doi.org/10.1063/1.4966812
Mostapha, Marhaini ; Jahar, Noorhasmiera Abu ; Chin, Siew Xian ; Syed Jaafar, Sharifah Nabihah ; Zakaria, Sarani ; Wan Kamaruddin, Wan Mohd Aizat ; Azizan, Kamalrul Azlan. / Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis. 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium. Vol. 1784 American Institute of Physics Inc., 2016.
@inproceedings{402f8a89f7674dcb9f624a6c22d2e76d,
title = "Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis",
abstract = "The effectiveness in the dehydration of sugars into 5-Hydroxymethylfurfural is related to the catalyst existence. A comprehensive synthesis of 5-Hydroxymethylfurfural from fructose, glucose and sucrose (3.73 mmol) with and without addition zeolite catalyst was performed in this study. The reactions were carried out in water-methanol solvent system for 3 hours reaction time at 180°C temperature. The catalytic results from HPLC showed that the reaction with zeolite increases the yield of 5-Hydroxymethylfurfural with 51.72 {\%}, 34.01{\%} and 50.10{\%} for fructose, glucose and sucrose respectively. The study suggests that zeolites promote the isomerization of glucose into fructose to occur and simultaneously catalyze the dehydration of fructose into 5-Hydroxymethylfurfural. Only slight changes on FT-IR spectra of use zeolite after the reaction was observed. Thus suggest that zeolite was a potential catalyst for catalytic reaction for the conversion of sugar into 5-Hydroxymethylfurfural.",
keywords = "Fructose, glucose, HPLC, solid catalyst, sucrose",
author = "Marhaini Mostapha and Jahar, {Noorhasmiera Abu} and Chin, {Siew Xian} and {Syed Jaafar}, {Sharifah Nabihah} and Sarani Zakaria and {Wan Kamaruddin}, {Wan Mohd Aizat} and Azizan, {Kamalrul Azlan}",
year = "2016",
month = "11",
day = "17",
doi = "10.1063/1.4966812",
language = "English",
volume = "1784",
booktitle = "2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium",
publisher = "American Institute of Physics Inc.",

}

TY - GEN

T1 - Effect of zeolite catalyst on sugar dehydration for 5-Hydroxymethylfurfural synthesis

AU - Mostapha, Marhaini

AU - Jahar, Noorhasmiera Abu

AU - Chin, Siew Xian

AU - Syed Jaafar, Sharifah Nabihah

AU - Zakaria, Sarani

AU - Wan Kamaruddin, Wan Mohd Aizat

AU - Azizan, Kamalrul Azlan

PY - 2016/11/17

Y1 - 2016/11/17

N2 - The effectiveness in the dehydration of sugars into 5-Hydroxymethylfurfural is related to the catalyst existence. A comprehensive synthesis of 5-Hydroxymethylfurfural from fructose, glucose and sucrose (3.73 mmol) with and without addition zeolite catalyst was performed in this study. The reactions were carried out in water-methanol solvent system for 3 hours reaction time at 180°C temperature. The catalytic results from HPLC showed that the reaction with zeolite increases the yield of 5-Hydroxymethylfurfural with 51.72 %, 34.01% and 50.10% for fructose, glucose and sucrose respectively. The study suggests that zeolites promote the isomerization of glucose into fructose to occur and simultaneously catalyze the dehydration of fructose into 5-Hydroxymethylfurfural. Only slight changes on FT-IR spectra of use zeolite after the reaction was observed. Thus suggest that zeolite was a potential catalyst for catalytic reaction for the conversion of sugar into 5-Hydroxymethylfurfural.

AB - The effectiveness in the dehydration of sugars into 5-Hydroxymethylfurfural is related to the catalyst existence. A comprehensive synthesis of 5-Hydroxymethylfurfural from fructose, glucose and sucrose (3.73 mmol) with and without addition zeolite catalyst was performed in this study. The reactions were carried out in water-methanol solvent system for 3 hours reaction time at 180°C temperature. The catalytic results from HPLC showed that the reaction with zeolite increases the yield of 5-Hydroxymethylfurfural with 51.72 %, 34.01% and 50.10% for fructose, glucose and sucrose respectively. The study suggests that zeolites promote the isomerization of glucose into fructose to occur and simultaneously catalyze the dehydration of fructose into 5-Hydroxymethylfurfural. Only slight changes on FT-IR spectra of use zeolite after the reaction was observed. Thus suggest that zeolite was a potential catalyst for catalytic reaction for the conversion of sugar into 5-Hydroxymethylfurfural.

KW - Fructose

KW - glucose

KW - HPLC

KW - solid catalyst

KW - sucrose

UR - http://www.scopus.com/inward/record.url?scp=85014698829&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85014698829&partnerID=8YFLogxK

U2 - 10.1063/1.4966812

DO - 10.1063/1.4966812

M3 - Conference contribution

VL - 1784

BT - 2016 UKM FST Postgraduate Colloquium: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2016 Postgraduate Colloquium

PB - American Institute of Physics Inc.

ER -