Effect of nickel composition and preparation method for production of hydrogen via glycerol steam reforming

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

The need and development of cleaner and greener alternative technologies using the heterogeneous catalytic system in the synthesis of fuel is very important. In this work hydrogen production via steam reforming of glycerol (C3H8O3) was carried out over nickel supported on hydroxyapatite [Ca5(PO4)3(OH)] as a biomaterial catalyst. The time reaction is carried out for 240 minutes in a fixed-bed reactor fixed at 600 °C and atmospheric pressure with the water-to-glycerol feed ratio of 8:1. Catalysts were prepared by mean of impregnation and sol-gel method with varied nickel loadings (3, 6, 9, 12 %) on hydroxyapatite. The catalysts were characterized by BET surface area, X-ray diffraction, and SEM-EDX techniques. It is found that 3 wt% of nickel loading prepared via sol-gel method exhibit the higher hydrogen production rates (63.62 %-74.16 %) in comparison to the other nickel loadings.

Original languageEnglish
Title of host publicationKey Engineering Materials
Pages1046-1051
Number of pages6
Volume471-472
DOIs
Publication statusPublished - 2011
Event8th International Conference on Composite Science and Technology, ICCST8 - Kuala Lumpur
Duration: 22 Mar 201124 Mar 2011

Publication series

NameKey Engineering Materials
Volume471-472
ISSN (Print)10139826

Other

Other8th International Conference on Composite Science and Technology, ICCST8
CityKuala Lumpur
Period22/3/1124/3/11

Fingerprint

Steam reforming
Nickel
Glycerol
Hydrogen
Durapatite
Hydrogen production
Chemical analysis
Hydroxyapatite
Sol-gel process
Catalysts
Biocompatible Materials
Biomaterials
Impregnation
Atmospheric pressure
Energy dispersive spectroscopy
X ray diffraction
Scanning electron microscopy
Water

Keywords

  • Glycerol
  • Hydrogen production
  • Impregnation
  • Nickel /hydroxyapatite catalyst
  • Sol-gel
  • Steam reforming
  • Surface area

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Effect of nickel composition and preparation method for production of hydrogen via glycerol steam reforming. / Hakim, Lukman; Yaakob, Zahira; Ismail, Manal; Wan Daud, Wan Ramli; Herianto, Edy.

Key Engineering Materials. Vol. 471-472 2011. p. 1046-1051 (Key Engineering Materials; Vol. 471-472).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Hakim, L, Yaakob, Z, Ismail, M, Wan Daud, WR & Herianto, E 2011, Effect of nickel composition and preparation method for production of hydrogen via glycerol steam reforming. in Key Engineering Materials. vol. 471-472, Key Engineering Materials, vol. 471-472, pp. 1046-1051, 8th International Conference on Composite Science and Technology, ICCST8, Kuala Lumpur, 22/3/11. https://doi.org/10.4028/www.scientific.net/KEM.471-472.1046
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