Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100% and 1,2-PDO selectivity of 94% respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established.

Original languageEnglish
Title of host publicationCurrent Material Research Using X-Rays and Related Techniques II
PublisherTrans Tech Publications Ltd
Pages496-502
Number of pages7
Volume888 MSF
ISBN (Print)9783035710298
DOIs
Publication statusPublished - 2017
EventInternational Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016 - Putrajaya, Malaysia
Duration: 17 Aug 201618 Aug 2016

Publication series

NameMaterials Science Forum
Volume888 MSF
ISSN (Print)02555476

Other

OtherInternational Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016
CountryMalaysia
CityPutrajaya
Period17/8/1618/8/16

Fingerprint

Propylene Glycol
Fluorine
glycerols
Tin oxides
Glycerol
compatibility
tin oxides
fluorine
Metals
catalysts
Catalysts
Ruthenium
metals
ruthenium
Osmium
hydrogenolysis
Hydrogenolysis
Acetaldehyde
osmium
acetaldehyde

Keywords

  • 1,2-propanediol
  • Compatibility
  • Fluorine-doped tin oxide (FTO)
  • Glycerol conversion
  • Metal

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Samad, W. Z., Wan Nor Roslam, W. I., Hamzah, N., Yarmo, M. A., & Yusop, M. R. (2017). Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol. In Current Material Research Using X-Rays and Related Techniques II (Vol. 888 MSF, pp. 496-502). (Materials Science Forum; Vol. 888 MSF). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/MSF.888.496

Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol. / Samad, Wan Zurina; Wan Nor Roslam, Wan Isahak; Hamzah, Noraini; Yarmo, Mohd. Ambar; Yusop, Muhammad Rahimi.

Current Material Research Using X-Rays and Related Techniques II. Vol. 888 MSF Trans Tech Publications Ltd, 2017. p. 496-502 (Materials Science Forum; Vol. 888 MSF).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Samad, WZ, Wan Nor Roslam, WI, Hamzah, N, Yarmo, MA & Yusop, MR 2017, Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol. in Current Material Research Using X-Rays and Related Techniques II. vol. 888 MSF, Materials Science Forum, vol. 888 MSF, Trans Tech Publications Ltd, pp. 496-502, International Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016, Putrajaya, Malaysia, 17/8/16. https://doi.org/10.4028/www.scientific.net/MSF.888.496
Samad WZ, Wan Nor Roslam WI, Hamzah N, Yarmo MA, Yusop MR. Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol. In Current Material Research Using X-Rays and Related Techniques II. Vol. 888 MSF. Trans Tech Publications Ltd. 2017. p. 496-502. (Materials Science Forum). https://doi.org/10.4028/www.scientific.net/MSF.888.496
Samad, Wan Zurina ; Wan Nor Roslam, Wan Isahak ; Hamzah, Noraini ; Yarmo, Mohd. Ambar ; Yusop, Muhammad Rahimi. / Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol. Current Material Research Using X-Rays and Related Techniques II. Vol. 888 MSF Trans Tech Publications Ltd, 2017. pp. 496-502 (Materials Science Forum).
@inproceedings{251e4d7ec1e7489ba74f39b8115dcbf7,
title = "Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol",
abstract = "The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100{\%} and 1,2-PDO selectivity of 94{\%} respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established.",
keywords = "1,2-propanediol, Compatibility, Fluorine-doped tin oxide (FTO), Glycerol conversion, Metal",
author = "Samad, {Wan Zurina} and {Wan Nor Roslam}, {Wan Isahak} and Noraini Hamzah and Yarmo, {Mohd. Ambar} and Yusop, {Muhammad Rahimi}",
year = "2017",
doi = "10.4028/www.scientific.net/MSF.888.496",
language = "English",
isbn = "9783035710298",
volume = "888 MSF",
series = "Materials Science Forum",
publisher = "Trans Tech Publications Ltd",
pages = "496--502",
booktitle = "Current Material Research Using X-Rays and Related Techniques II",

}

TY - GEN

T1 - Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol

AU - Samad, Wan Zurina

AU - Wan Nor Roslam, Wan Isahak

AU - Hamzah, Noraini

AU - Yarmo, Mohd. Ambar

AU - Yusop, Muhammad Rahimi

PY - 2017

Y1 - 2017

N2 - The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100% and 1,2-PDO selectivity of 94% respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established.

AB - The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100% and 1,2-PDO selectivity of 94% respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established.

KW - 1,2-propanediol

KW - Compatibility

KW - Fluorine-doped tin oxide (FTO)

KW - Glycerol conversion

KW - Metal

UR - http://www.scopus.com/inward/record.url?scp=85014885544&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85014885544&partnerID=8YFLogxK

U2 - 10.4028/www.scientific.net/MSF.888.496

DO - 10.4028/www.scientific.net/MSF.888.496

M3 - Conference contribution

SN - 9783035710298

VL - 888 MSF

T3 - Materials Science Forum

SP - 496

EP - 502

BT - Current Material Research Using X-Rays and Related Techniques II

PB - Trans Tech Publications Ltd

ER -