Effect of ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide on the properties of poly(glycidyl methacrylate) based solid polymer electrolytes

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2 Citations (Scopus)

Abstract

A free standing polymer electrolytes films, containing poly(glycidyl methacrylate) (PGMA) as the polymer host, lithium perchlorate (LiClO4), and ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide [Bmim][TFSI] as a plasticizer was successfully prepared via the solution casting method. The XRD analysis revealed the amorphous nature of the electrolyte. ATR-FTIR and thermal studies confirmed the interaction and complexation between the polymer host and the ionic liquid. The maximum ionic conductivity of the solid polymer electrolyte was found at 2.56 × 10–5 S cm–1 by the addition of 60 wt % [Bmim][TFSI] at room temperature and increased up to 3.19 × 10–4 S cm–1 at 373 K, as well as exhibited a transition of temperature dependence of conductivity: Arrhenius-like behavior at low and high temperatures.

Original languageEnglish
Pages (from-to)362-373
Number of pages12
JournalRussian Journal of Electrochemistry
Volume52
Issue number4
DOIs
Publication statusPublished - 1 Apr 2016

Fingerprint

Ionic Liquids
Ionic liquids
Electrolytes
Polymers
Plasticizers
Ionic conductivity
Complexation
Temperature
Casting
Lithium
1-butyl-3-methylimidazolium
bis(trifluoromethanesulfonyl)imide
polyglycidyl methacrylate
lithium perchlorate

Keywords

  • 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide
  • ionic liquid
  • poly(glycidyl methacrylate)
  • solid polymer electrolyte

ASJC Scopus subject areas

  • Electrochemistry

Cite this

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title = "Effect of ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide on the properties of poly(glycidyl methacrylate) based solid polymer electrolytes",
abstract = "A free standing polymer electrolytes films, containing poly(glycidyl methacrylate) (PGMA) as the polymer host, lithium perchlorate (LiClO4), and ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide [Bmim][TFSI] as a plasticizer was successfully prepared via the solution casting method. The XRD analysis revealed the amorphous nature of the electrolyte. ATR-FTIR and thermal studies confirmed the interaction and complexation between the polymer host and the ionic liquid. The maximum ionic conductivity of the solid polymer electrolyte was found at 2.56 × 10–5 S cm–1 by the addition of 60 wt {\%} [Bmim][TFSI] at room temperature and increased up to 3.19 × 10–4 S cm–1 at 373 K, as well as exhibited a transition of temperature dependence of conductivity: Arrhenius-like behavior at low and high temperatures.",
keywords = "1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, ionic liquid, poly(glycidyl methacrylate), solid polymer electrolyte",
author = "Nabilah, {M. R N} and Alwi, {M. A.} and Su'ait, {Mohd Sukor} and M. Imperiyka and {Abu Hanifah}, Sharina and Azizan Ahmad and Hassan, {Nur Hasyareeda} and {Abd Rahman}, {Mohd Yusri}",
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doi = "10.1134/S1023193516040091",
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AU - Nabilah, M. R N

AU - Alwi, M. A.

AU - Su'ait, Mohd Sukor

AU - Imperiyka, M.

AU - Abu Hanifah, Sharina

AU - Ahmad, Azizan

AU - Hassan, Nur Hasyareeda

AU - Abd Rahman, Mohd Yusri

PY - 2016/4/1

Y1 - 2016/4/1

N2 - A free standing polymer electrolytes films, containing poly(glycidyl methacrylate) (PGMA) as the polymer host, lithium perchlorate (LiClO4), and ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide [Bmim][TFSI] as a plasticizer was successfully prepared via the solution casting method. The XRD analysis revealed the amorphous nature of the electrolyte. ATR-FTIR and thermal studies confirmed the interaction and complexation between the polymer host and the ionic liquid. The maximum ionic conductivity of the solid polymer electrolyte was found at 2.56 × 10–5 S cm–1 by the addition of 60 wt % [Bmim][TFSI] at room temperature and increased up to 3.19 × 10–4 S cm–1 at 373 K, as well as exhibited a transition of temperature dependence of conductivity: Arrhenius-like behavior at low and high temperatures.

AB - A free standing polymer electrolytes films, containing poly(glycidyl methacrylate) (PGMA) as the polymer host, lithium perchlorate (LiClO4), and ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide [Bmim][TFSI] as a plasticizer was successfully prepared via the solution casting method. The XRD analysis revealed the amorphous nature of the electrolyte. ATR-FTIR and thermal studies confirmed the interaction and complexation between the polymer host and the ionic liquid. The maximum ionic conductivity of the solid polymer electrolyte was found at 2.56 × 10–5 S cm–1 by the addition of 60 wt % [Bmim][TFSI] at room temperature and increased up to 3.19 × 10–4 S cm–1 at 373 K, as well as exhibited a transition of temperature dependence of conductivity: Arrhenius-like behavior at low and high temperatures.

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