Effect of Germanium addition to Sn3.5Ag lead free solder system for overall BGA package robustness improvement

Eu Poh Leng, Wong Tzu Ling, Min Ding, Nowshad Amin, Ibrahim Ahmad, Tay Yee Han, A. S M A Haseeb

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A study was conducted on BGA lead-free C5 solder joint system to assess the effect of Germanium addition to Sn3.5Ag solder alloy through comparison study of Sn3.5Ag vs. Sn3.5AgGe. The main objective of this study is to find a way to resolve solder surface oxidation after thermal processes, while determining if there's any adverse effect on the solder joint by Germanium addition. The result of this study showed that addition of Germanium in Sn3.5Ag C5 solder system resolved solder surface oxidation after thermal processes, without any negative impact to the solder joint and solderability. Experimental works were carried out to observe the melting properties and solder surface morphology by Differential Scanning Calorimetry (DSC) and SEM. Solder surface oxidation was measured by EDX. Shear and pull strength was measured by Dage which is representative of the intermetallic (IMC) strength between the C5 solder sphere and Cu/Ni/Au pad finishing. Solderability test was conducted per Jedec standard. Tray and Packaging Drop Tests were done to gauge solder joint performance against impact force. A comprehensive study was done to study the effect of microstructure and interface intermetallic of both solder system at ambient, high temperature storage (HTS) at 150°C for 24, 48, 96, 168, 504 and 2000 hours and multiple reflow of 1x, 2x, 3x, 6x towards the joint integrity. In each read point, Sn3.5AgGe has significantly higher ball shear and ball pull strength. EPMA microstructure analysis after cross-sectioning on bulk solder and IMC revealed traces of Germanium that contributed to the significant increase in ball shear and ball pull strength, while did not cause any bulk solder and IMC morphology changes. Both solderability and drop test passed. In conclusion, addition of Germanium in Sn3.5Ag lead-free solder is able to resolve surface oxidation problem after thermal processing, with improvement in solder joint strength for overall lead-free package robustness.

Original languageEnglish
Title of host publicationProceedings - 2009 International Symposium on Microelectronics, IMAPS 2009
Pages150-157
Number of pages8
Publication statusPublished - 2009
Event42nd International Symposium on Microelectronics, IMAPS 2009 - San Jose, CA
Duration: 1 Nov 20095 Nov 2009

Other

Other42nd International Symposium on Microelectronics, IMAPS 2009
CitySan Jose, CA
Period1/11/095/11/09

Fingerprint

Germanium
Soldering alloys
Intermetallics
Oxidation
Lead-free solders
Microstructure
Electron probe microanalysis
Gages
Surface morphology
Energy dispersive spectroscopy
Differential scanning calorimetry
Packaging
Melting
Lead

Keywords

  • BGA packaging
  • Germanium
  • Intermetallic
  • Lead-free C5
  • Shear and pull strength
  • Sn3.5Ag
  • Surface oxidation

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

Cite this

Leng, E. P., Ling, W. T., Ding, M., Amin, N., Ahmad, I., Han, T. Y., & Haseeb, A. S. M. A. (2009). Effect of Germanium addition to Sn3.5Ag lead free solder system for overall BGA package robustness improvement. In Proceedings - 2009 International Symposium on Microelectronics, IMAPS 2009 (pp. 150-157)

Effect of Germanium addition to Sn3.5Ag lead free solder system for overall BGA package robustness improvement. / Leng, Eu Poh; Ling, Wong Tzu; Ding, Min; Amin, Nowshad; Ahmad, Ibrahim; Han, Tay Yee; Haseeb, A. S M A.

Proceedings - 2009 International Symposium on Microelectronics, IMAPS 2009. 2009. p. 150-157.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Leng, EP, Ling, WT, Ding, M, Amin, N, Ahmad, I, Han, TY & Haseeb, ASMA 2009, Effect of Germanium addition to Sn3.5Ag lead free solder system for overall BGA package robustness improvement. in Proceedings - 2009 International Symposium on Microelectronics, IMAPS 2009. pp. 150-157, 42nd International Symposium on Microelectronics, IMAPS 2009, San Jose, CA, 1/11/09.
Leng EP, Ling WT, Ding M, Amin N, Ahmad I, Han TY et al. Effect of Germanium addition to Sn3.5Ag lead free solder system for overall BGA package robustness improvement. In Proceedings - 2009 International Symposium on Microelectronics, IMAPS 2009. 2009. p. 150-157
Leng, Eu Poh ; Ling, Wong Tzu ; Ding, Min ; Amin, Nowshad ; Ahmad, Ibrahim ; Han, Tay Yee ; Haseeb, A. S M A. / Effect of Germanium addition to Sn3.5Ag lead free solder system for overall BGA package robustness improvement. Proceedings - 2009 International Symposium on Microelectronics, IMAPS 2009. 2009. pp. 150-157
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abstract = "A study was conducted on BGA lead-free C5 solder joint system to assess the effect of Germanium addition to Sn3.5Ag solder alloy through comparison study of Sn3.5Ag vs. Sn3.5AgGe. The main objective of this study is to find a way to resolve solder surface oxidation after thermal processes, while determining if there's any adverse effect on the solder joint by Germanium addition. The result of this study showed that addition of Germanium in Sn3.5Ag C5 solder system resolved solder surface oxidation after thermal processes, without any negative impact to the solder joint and solderability. Experimental works were carried out to observe the melting properties and solder surface morphology by Differential Scanning Calorimetry (DSC) and SEM. Solder surface oxidation was measured by EDX. Shear and pull strength was measured by Dage which is representative of the intermetallic (IMC) strength between the C5 solder sphere and Cu/Ni/Au pad finishing. Solderability test was conducted per Jedec standard. Tray and Packaging Drop Tests were done to gauge solder joint performance against impact force. A comprehensive study was done to study the effect of microstructure and interface intermetallic of both solder system at ambient, high temperature storage (HTS) at 150°C for 24, 48, 96, 168, 504 and 2000 hours and multiple reflow of 1x, 2x, 3x, 6x towards the joint integrity. In each read point, Sn3.5AgGe has significantly higher ball shear and ball pull strength. EPMA microstructure analysis after cross-sectioning on bulk solder and IMC revealed traces of Germanium that contributed to the significant increase in ball shear and ball pull strength, while did not cause any bulk solder and IMC morphology changes. Both solderability and drop test passed. In conclusion, addition of Germanium in Sn3.5Ag lead-free solder is able to resolve surface oxidation problem after thermal processing, with improvement in solder joint strength for overall lead-free package robustness.",
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AU - Ahmad, Ibrahim

AU - Han, Tay Yee

AU - Haseeb, A. S M A

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N2 - A study was conducted on BGA lead-free C5 solder joint system to assess the effect of Germanium addition to Sn3.5Ag solder alloy through comparison study of Sn3.5Ag vs. Sn3.5AgGe. The main objective of this study is to find a way to resolve solder surface oxidation after thermal processes, while determining if there's any adverse effect on the solder joint by Germanium addition. The result of this study showed that addition of Germanium in Sn3.5Ag C5 solder system resolved solder surface oxidation after thermal processes, without any negative impact to the solder joint and solderability. Experimental works were carried out to observe the melting properties and solder surface morphology by Differential Scanning Calorimetry (DSC) and SEM. Solder surface oxidation was measured by EDX. Shear and pull strength was measured by Dage which is representative of the intermetallic (IMC) strength between the C5 solder sphere and Cu/Ni/Au pad finishing. Solderability test was conducted per Jedec standard. Tray and Packaging Drop Tests were done to gauge solder joint performance against impact force. A comprehensive study was done to study the effect of microstructure and interface intermetallic of both solder system at ambient, high temperature storage (HTS) at 150°C for 24, 48, 96, 168, 504 and 2000 hours and multiple reflow of 1x, 2x, 3x, 6x towards the joint integrity. In each read point, Sn3.5AgGe has significantly higher ball shear and ball pull strength. EPMA microstructure analysis after cross-sectioning on bulk solder and IMC revealed traces of Germanium that contributed to the significant increase in ball shear and ball pull strength, while did not cause any bulk solder and IMC morphology changes. Both solderability and drop test passed. In conclusion, addition of Germanium in Sn3.5Ag lead-free solder is able to resolve surface oxidation problem after thermal processing, with improvement in solder joint strength for overall lead-free package robustness.

AB - A study was conducted on BGA lead-free C5 solder joint system to assess the effect of Germanium addition to Sn3.5Ag solder alloy through comparison study of Sn3.5Ag vs. Sn3.5AgGe. The main objective of this study is to find a way to resolve solder surface oxidation after thermal processes, while determining if there's any adverse effect on the solder joint by Germanium addition. The result of this study showed that addition of Germanium in Sn3.5Ag C5 solder system resolved solder surface oxidation after thermal processes, without any negative impact to the solder joint and solderability. Experimental works were carried out to observe the melting properties and solder surface morphology by Differential Scanning Calorimetry (DSC) and SEM. Solder surface oxidation was measured by EDX. Shear and pull strength was measured by Dage which is representative of the intermetallic (IMC) strength between the C5 solder sphere and Cu/Ni/Au pad finishing. Solderability test was conducted per Jedec standard. Tray and Packaging Drop Tests were done to gauge solder joint performance against impact force. A comprehensive study was done to study the effect of microstructure and interface intermetallic of both solder system at ambient, high temperature storage (HTS) at 150°C for 24, 48, 96, 168, 504 and 2000 hours and multiple reflow of 1x, 2x, 3x, 6x towards the joint integrity. In each read point, Sn3.5AgGe has significantly higher ball shear and ball pull strength. EPMA microstructure analysis after cross-sectioning on bulk solder and IMC revealed traces of Germanium that contributed to the significant increase in ball shear and ball pull strength, while did not cause any bulk solder and IMC morphology changes. Both solderability and drop test passed. In conclusion, addition of Germanium in Sn3.5Ag lead-free solder is able to resolve surface oxidation problem after thermal processing, with improvement in solder joint strength for overall lead-free package robustness.

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