(E)-2-[1-(1-Benzothio-phen-3-yl)ethyl-idene]hydrazinecarbothio-amide methanol hemisolvate

Safaa Fares Kayed, Yang Farina Abdul Aziz, Mohammad Kassim, Jim Simpson

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The asymmetric unit of the title compound, C11H11N3S2·0.5CH4O, contains four thio-semicarbazone mol-ecules and two methanol solvent mol-ecules. Each hydrazinecarbothio-amide mol-ecule adopts an E configuration with respect to the C=N double bond and is stabilized by an intra-molecular N - H⋯N hydrogen bond, resulting in an S(5) ring motif. In the crystal structure, an extensive network of N - H⋯O, N - H⋯N, O - H⋯S and N - H⋯S hydrogen bonds and weak C - H⋯O, C - H⋯N and C - H⋯S contacts together with an S⋯S [3.5958 (14) Å] and a C - H⋯π inter-action form a three-dimensional network.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number6
DOIs
Publication statusPublished - 2008

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Amides
amides
Methanol
Hydrogen bonds
methyl alcohol
Semicarbazones
hydrogen bonds
Crystal structure
crystal structure
rings
configurations

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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title = "(E)-2-[1-(1-Benzothio-phen-3-yl)ethyl-idene]hydrazinecarbothio-amide methanol hemisolvate",
abstract = "The asymmetric unit of the title compound, C11H11N3S2·0.5CH4O, contains four thio-semicarbazone mol-ecules and two methanol solvent mol-ecules. Each hydrazinecarbothio-amide mol-ecule adopts an E configuration with respect to the C=N double bond and is stabilized by an intra-molecular N - H⋯N hydrogen bond, resulting in an S(5) ring motif. In the crystal structure, an extensive network of N - H⋯O, N - H⋯N, O - H⋯S and N - H⋯S hydrogen bonds and weak C - H⋯O, C - H⋯N and C - H⋯S contacts together with an S⋯S [3.5958 (14) {\AA}] and a C - H⋯π inter-action form a three-dimensional network.",
author = "Kayed, {Safaa Fares} and {Abdul Aziz}, {Yang Farina} and Mohammad Kassim and Jim Simpson",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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publisher = "International Union of Crystallography",
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TY - JOUR

T1 - (E)-2-[1-(1-Benzothio-phen-3-yl)ethyl-idene]hydrazinecarbothio-amide methanol hemisolvate

AU - Kayed, Safaa Fares

AU - Abdul Aziz, Yang Farina

AU - Kassim, Mohammad

AU - Simpson, Jim

PY - 2008

Y1 - 2008

N2 - The asymmetric unit of the title compound, C11H11N3S2·0.5CH4O, contains four thio-semicarbazone mol-ecules and two methanol solvent mol-ecules. Each hydrazinecarbothio-amide mol-ecule adopts an E configuration with respect to the C=N double bond and is stabilized by an intra-molecular N - H⋯N hydrogen bond, resulting in an S(5) ring motif. In the crystal structure, an extensive network of N - H⋯O, N - H⋯N, O - H⋯S and N - H⋯S hydrogen bonds and weak C - H⋯O, C - H⋯N and C - H⋯S contacts together with an S⋯S [3.5958 (14) Å] and a C - H⋯π inter-action form a three-dimensional network.

AB - The asymmetric unit of the title compound, C11H11N3S2·0.5CH4O, contains four thio-semicarbazone mol-ecules and two methanol solvent mol-ecules. Each hydrazinecarbothio-amide mol-ecule adopts an E configuration with respect to the C=N double bond and is stabilized by an intra-molecular N - H⋯N hydrogen bond, resulting in an S(5) ring motif. In the crystal structure, an extensive network of N - H⋯O, N - H⋯N, O - H⋯S and N - H⋯S hydrogen bonds and weak C - H⋯O, C - H⋯N and C - H⋯S contacts together with an S⋯S [3.5958 (14) Å] and a C - H⋯π inter-action form a three-dimensional network.

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U2 - 10.1107/S160053680801297X

DO - 10.1107/S160053680801297X

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VL - 64

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 6

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