Dichloromethyl[1-(2-pyridyl)ethanone benzoylhydrazonato]tin(IV)

M. A. Affan, Mustaffa B. Shamsuddin, M. Sukeri M Yusof, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The chelate Sn - O - C - N - N - C - C - N fragment, together with the substituent methyl C atom, in the title complex, [SnCl2(CH 3)(C14H12N3O)], is planar, allowing the tridentate O,N,N-donor atoms and the methyl ligand C atom to occupy the equatorial positions in an octahedral environment. The geometry of the Sn atom is distorted octahedral, with a Cl - Sn - Cl axial bond angle of 172.02 (3)°.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number1
DOIs
Publication statusPublished - Jan 2004

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Tin
tin
Ligands
Atoms
atoms
chelates
fragments
methylidyne
ligands
Geometry
geometry

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Dichloromethyl[1-(2-pyridyl)ethanone benzoylhydrazonato]tin(IV). / Affan, M. A.; Shamsuddin, Mustaffa B.; Yusof, M. Sukeri M; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 1, 01.2004.

Research output: Contribution to journalArticle

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AU - Mohd. Yamin, Bohari

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AB - The chelate Sn - O - C - N - N - C - C - N fragment, together with the substituent methyl C atom, in the title complex, [SnCl2(CH 3)(C14H12N3O)], is planar, allowing the tridentate O,N,N-donor atoms and the methyl ligand C atom to occupy the equatorial positions in an octahedral environment. The geometry of the Sn atom is distorted octahedral, with a Cl - Sn - Cl axial bond angle of 172.02 (3)°.

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