Di-n-butylbis (N-ethyl-N-phenyldithiocarbamato-κS)tin(IV)

Kamaludin Nurul Farahana, Ibrahim Baba, Normah Awang, Mohamed Ibrahim Mohamed Tahir, Edward R T Tiekink

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, [Sn(C 4H 9) 2(C 9H 10NS 2) 2], features a tetrahedrally coordinated Sn IV atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn IVatom [3.0136(7) and 2.9865(8) Å], giving rise to distortions from the ideal geometry as evident in the wide C-Sn-C bond angle of 139.06(12)°. In the crystal, C-H···S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C-H···π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number1
DOIs
Publication statusPublished - Jan 2012

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Tin
tin
Thiones
Atoms
Ligands
Crystals
atoms
Geometry
interactions
ligands
geometry
crystals

Keywords

  • Data-to-parameter ratio = 19.6
  • Disorder in main residue
  • Mean σ(C-C) = 0.005 Å
  • R factor = 0.030
  • Single-crystal X-ray study
  • T = 150 K
  • wR factor = 0.074

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Di-n-butylbis (N-ethyl-N-phenyldithiocarbamato-κS)tin(IV). / Nurul Farahana, Kamaludin; Baba, Ibrahim; Awang, Normah; Tahir, Mohamed Ibrahim Mohamed; Tiekink, Edward R T.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 1, 01.2012.

Research output: Contribution to journalArticle

Nurul Farahana, Kamaludin ; Baba, Ibrahim ; Awang, Normah ; Tahir, Mohamed Ibrahim Mohamed ; Tiekink, Edward R T. / Di-n-butylbis (N-ethyl-N-phenyldithiocarbamato-κS)tin(IV). In: Acta Crystallographica Section E: Structure Reports Online. 2012 ; Vol. 68, No. 1.
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AU - Tahir, Mohamed Ibrahim Mohamed

AU - Tiekink, Edward R T

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N2 - The title compound, [Sn(C 4H 9) 2(C 9H 10NS 2) 2], features a tetrahedrally coordinated Sn IV atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn IVatom [3.0136(7) and 2.9865(8) Å], giving rise to distortions from the ideal geometry as evident in the wide C-Sn-C bond angle of 139.06(12)°. In the crystal, C-H···S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C-H···π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites.

AB - The title compound, [Sn(C 4H 9) 2(C 9H 10NS 2) 2], features a tetrahedrally coordinated Sn IV atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn IVatom [3.0136(7) and 2.9865(8) Å], giving rise to distortions from the ideal geometry as evident in the wide C-Sn-C bond angle of 139.06(12)°. In the crystal, C-H···S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C-H···π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites.

KW - Data-to-parameter ratio = 19.6

KW - Disorder in main residue

KW - Mean σ(C-C) = 0.005 Å

KW - R factor = 0.030

KW - Single-crystal X-ray study

KW - T = 150 K

KW - wR factor = 0.074

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