Development of new corrosion inhibitor tested on mild steel supported by electrochemical study

Hussein Jwad Habeeb, Hasan Mohammed Luaibi, Rifaat Mohammed Dakhil, Abdul Amir H. Kadhum, Ahmed A. Al-Amiery, Tayser Sumer Gaaz

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Mild steel is a metal which is commonly used in industrials and manufacturing of equipment for most industries round the world. It is cheaper cost compared with the other metals and its durable, hard and easy-to-wear physical properties make it a major choice in the manufacture of equipment parts. The main problem through the uses of mild steel in industry is its resistance against corrosion, especially in acidic solutions. This case led to raise the cost of maintenance of equipment that used mild steel and as a result increased costs for the company. Organic corrosive inhibitors that also act as green chemicals, 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazol have been synthesized. This inhibitor is tested as corrosion inhibitor on a mild steel sample MS in 1 M hydrochloric acid solution (HCl) using electrochemical measurements test includes PD (Potentiodynamic), EIS (Electrochemical impedance spectroscopy), OCP (Open circuit potential) and EFM (electrochemical frequency modulation). The obtained results indicate that 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazol acts as a good corrosion inhibitor for mild steel sample in HCl solution with efficiency above 90%. Changes in the impedance parameters postulated adsorption on the mild steel specimens' surfaces of, which it going to the formation of protective coating layer. It also shows that 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazol corrosion inhibitors are effective in helping to reduce and slow down the corrosion process that occurs on mild steel surface in hydrochloric acid solution. Increase of corrosion inhibitor concentration provides a protective layer of mild steel. However, this protective layer becomes weak when the temperature of the solution increases.

Original languageEnglish
Pages (from-to)1260-1267
Number of pages8
JournalResults in Physics
Volume8
DOIs
Publication statusPublished - 1 Mar 2018

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inhibitors
corrosion
steels
hydrochloric acid
costs
industries
impedance
protective coatings
corrosion resistance
metals
frequency modulation
maintenance
manufacturing
physical properties
adsorption
spectroscopy

Keywords

  • Electrochemical frequency modulation
  • Hydroxybenzylideneaminomethy
  • Impedance
  • Potentiodynamic

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Development of new corrosion inhibitor tested on mild steel supported by electrochemical study. / Habeeb, Hussein Jwad; Luaibi, Hasan Mohammed; Dakhil, Rifaat Mohammed; Kadhum, Abdul Amir H.; Al-Amiery, Ahmed A.; Gaaz, Tayser Sumer.

In: Results in Physics, Vol. 8, 01.03.2018, p. 1260-1267.

Research output: Contribution to journalArticle

Habeeb, Hussein Jwad ; Luaibi, Hasan Mohammed ; Dakhil, Rifaat Mohammed ; Kadhum, Abdul Amir H. ; Al-Amiery, Ahmed A. ; Gaaz, Tayser Sumer. / Development of new corrosion inhibitor tested on mild steel supported by electrochemical study. In: Results in Physics. 2018 ; Vol. 8. pp. 1260-1267.
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