Crystal structure of diiodobis(1-(6-methylpyridine-2-yl)thiourea-kS)mercury(II)

Aaina M. Azman, Maisara Abdul Kadir, Bohari Mohd. Yamin, M. Sukeri M Yusof

Research output: Contribution to journalArticle

Abstract

The structure of diiodobis(1-(6-methylpyridine-2-yl)thiourea-kS)mercury(II) was determined by X-ray crystallography. This complex crystallizes in the space group P21/c, with cell parameters a = 10.3151(7)Å, b = 16.8739(10)Å, c = 13.7609(7)Å, β = 113.614(4)°, Z = 4, and V = 2194.6(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0381 and wR2 = 0.0666. Two molecules of 1-(6-methylpyridin-2-yl)thiourea are coordinated to the mercury ions through monodentate sulfur atoms which leads to the formation of a distorted tetrahedral environment complex. 2016

Original languageEnglish
Pages (from-to)51-52
Number of pages2
JournalX-ray Structure Analysis Online
Volume32
Issue number11
Publication statusPublished - 2016

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Thiourea
Thioureas
Mercury
Crystal structure
X ray crystallography
Sulfur
Ions
Atoms
Molecules
2-picoline

ASJC Scopus subject areas

  • Analytical Chemistry
  • Materials Chemistry

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Crystal structure of diiodobis(1-(6-methylpyridine-2-yl)thiourea-kS)mercury(II). / Azman, Aaina M.; Kadir, Maisara Abdul; Mohd. Yamin, Bohari; Yusof, M. Sukeri M.

In: X-ray Structure Analysis Online, Vol. 32, No. 11, 2016, p. 51-52.

Research output: Contribution to journalArticle

Azman, Aaina M. ; Kadir, Maisara Abdul ; Mohd. Yamin, Bohari ; Yusof, M. Sukeri M. / Crystal structure of diiodobis(1-(6-methylpyridine-2-yl)thiourea-kS)mercury(II). In: X-ray Structure Analysis Online. 2016 ; Vol. 32, No. 11. pp. 51-52.
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AU - Yusof, M. Sukeri M

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N2 - The structure of diiodobis(1-(6-methylpyridine-2-yl)thiourea-kS)mercury(II) was determined by X-ray crystallography. This complex crystallizes in the space group P21/c, with cell parameters a = 10.3151(7)Å, b = 16.8739(10)Å, c = 13.7609(7)Å, β = 113.614(4)°, Z = 4, and V = 2194.6(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0381 and wR2 = 0.0666. Two molecules of 1-(6-methylpyridin-2-yl)thiourea are coordinated to the mercury ions through monodentate sulfur atoms which leads to the formation of a distorted tetrahedral environment complex. 2016

AB - The structure of diiodobis(1-(6-methylpyridine-2-yl)thiourea-kS)mercury(II) was determined by X-ray crystallography. This complex crystallizes in the space group P21/c, with cell parameters a = 10.3151(7)Å, b = 16.8739(10)Å, c = 13.7609(7)Å, β = 113.614(4)°, Z = 4, and V = 2194.6(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0381 and wR2 = 0.0666. Two molecules of 1-(6-methylpyridin-2-yl)thiourea are coordinated to the mercury ions through monodentate sulfur atoms which leads to the formation of a distorted tetrahedral environment complex. 2016

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