Crystal structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium

Karimah Kassim, Muhammad Ashraf Mohd Kahar, Bohari Mohd. Yamin, Mohd Abdul Fatah Abdul Manan, M. Sukeri M. Yusof

Research output: Contribution to journalArticle

Abstract

The structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium crystallized in a monoclinic system and was characterized thus: P21/c, a = 13.0221(14), b = 11.6615(13), c = 8.4898(9)Å, β = 97.327(4)°, Z = 2, V = 1278.7(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0349 [I > 2σ(I)] and wR2 = 0.0824. The molecules have two-fold symmetry about the centre Pd1 atom. Two ligands were coordinated to the Pd1 atom via oxygen and nitrogen atoms in a bidentate manner to form a square-planar geometrical structure.

Original languageEnglish
Pages (from-to)25-26
Number of pages2
JournalX-ray Structure Analysis Online
Volume35
Issue number4
DOIs
Publication statusPublished - 1 Jan 2019
Externally publishedYes

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Palladium
Crystal structure
Atoms
Nitrogen
Ligands
Oxygen
Molecules

ASJC Scopus subject areas

  • Analytical Chemistry
  • Materials Chemistry

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Crystal structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium. / Kassim, Karimah; Kahar, Muhammad Ashraf Mohd; Mohd. Yamin, Bohari; Manan, Mohd Abdul Fatah Abdul; Yusof, M. Sukeri M.

In: X-ray Structure Analysis Online, Vol. 35, No. 4, 01.01.2019, p. 25-26.

Research output: Contribution to journalArticle

Kassim, Karimah ; Kahar, Muhammad Ashraf Mohd ; Mohd. Yamin, Bohari ; Manan, Mohd Abdul Fatah Abdul ; Yusof, M. Sukeri M. / Crystal structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium. In: X-ray Structure Analysis Online. 2019 ; Vol. 35, No. 4. pp. 25-26.
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AU - Mohd. Yamin, Bohari

AU - Manan, Mohd Abdul Fatah Abdul

AU - Yusof, M. Sukeri M.

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N2 - The structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium crystallized in a monoclinic system and was characterized thus: P21/c, a = 13.0221(14), b = 11.6615(13), c = 8.4898(9)Å, β = 97.327(4)°, Z = 2, V = 1278.7(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0349 [I > 2σ(I)] and wR2 = 0.0824. The molecules have two-fold symmetry about the centre Pd1 atom. Two ligands were coordinated to the Pd1 atom via oxygen and nitrogen atoms in a bidentate manner to form a square-planar geometrical structure.

AB - The structure of bis(2-methoxy-6-((Z)-(p-tolylimino)methyl)phenoxy)palladium crystallized in a monoclinic system and was characterized thus: P21/c, a = 13.0221(14), b = 11.6615(13), c = 8.4898(9)Å, β = 97.327(4)°, Z = 2, V = 1278.7(2)Å3. The crystal structure was solved by direct methods and refined by full-matrix least-squares on F2 to final values of R1 = 0.0349 [I > 2σ(I)] and wR2 = 0.0824. The molecules have two-fold symmetry about the centre Pd1 atom. Two ligands were coordinated to the Pd1 atom via oxygen and nitrogen atoms in a bidentate manner to form a square-planar geometrical structure.

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