Cross metathesis of methyl oleate (MO) with terminal, internal olefins by ruthenium catalysts

Factors affecting the efficient MO conversion and the selectivity

Nor Wahida Awang, Ken Tsutsumi, Barbora Huštáková, Siti Fairus Mohd Yusoff, Kotohiro Nomura, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Cross metathesis (CM) reactions of methyl oleate (MO) with cis-4-octene (OC), cis-stilbene (CS) using RuCl2(PCy3)(IMesH2)(CHPh) [IMesH2 = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene; Cy = cyclohexyl] afforded CM products with high MO conversion and high selectivity under high molar (OC/MO, CS/MO) ratios; CM with cis-1,4-diacetoxy-2-butene also afforded metathesis products with high MO conversion under certain conditions. The efficient CM with allyltrimethylsilane proceeded with high activity, whereas the CM with glycidyl ether, β-pinene, and vanillylidenacetone proceeded with low MO conversion.

Original languageEnglish
Pages (from-to)100925-100930
Number of pages6
JournalRSC Advances
Volume6
Issue number103
DOIs
Publication statusPublished - 2016

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Ruthenium
Alkenes
Butenes
Olefins
Ethers
Catalysts
Stilbenes
methyl oleate

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Cross metathesis of methyl oleate (MO) with terminal, internal olefins by ruthenium catalysts : Factors affecting the efficient MO conversion and the selectivity. / Awang, Nor Wahida; Tsutsumi, Ken; Huštáková, Barbora; Mohd Yusoff, Siti Fairus; Nomura, Kotohiro; Mohd. Yamin, Bohari.

In: RSC Advances, Vol. 6, No. 103, 2016, p. 100925-100930.

Research output: Contribution to journalArticle

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AU - Nomura, Kotohiro

AU - Mohd. Yamin, Bohari

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