Cross metathesis of methyl oleate (MO) with terminal, internal olefins by ruthenium catalysts: Factors affecting the efficient MO conversion and the selectivity

Nor Wahida Awang, Ken Tsutsumi, Barbora Huštáková, Siti Fairus Mohd Yusoff, Kotohiro Nomura, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Cross metathesis (CM) reactions of methyl oleate (MO) with cis-4-octene (OC), cis-stilbene (CS) using RuCl2(PCy3)(IMesH2)(CHPh) [IMesH2 = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene; Cy = cyclohexyl] afforded CM products with high MO conversion and high selectivity under high molar (OC/MO, CS/MO) ratios; CM with cis-1,4-diacetoxy-2-butene also afforded metathesis products with high MO conversion under certain conditions. The efficient CM with allyltrimethylsilane proceeded with high activity, whereas the CM with glycidyl ether, β-pinene, and vanillylidenacetone proceeded with low MO conversion.

Original languageEnglish
Pages (from-to)100925-100930
Number of pages6
JournalRSC Advances
Volume6
Issue number103
DOIs
Publication statusPublished - 2016

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Ruthenium
Alkenes
Butenes
Olefins
Ethers
Catalysts
Stilbenes
methyl oleate

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Cross metathesis of methyl oleate (MO) with terminal, internal olefins by ruthenium catalysts : Factors affecting the efficient MO conversion and the selectivity. / Awang, Nor Wahida; Tsutsumi, Ken; Huštáková, Barbora; Mohd Yusoff, Siti Fairus; Nomura, Kotohiro; Mohd. Yamin, Bohari.

In: RSC Advances, Vol. 6, No. 103, 2016, p. 100925-100930.

Research output: Contribution to journalArticle

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AU - Nomura, Kotohiro

AU - Mohd. Yamin, Bohari

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