Conductivity and structural studies of pol(glycidyl methacrylate(GMA) -methyl methacrylate(MMA) -lithium triflate (LiCF3SO3) solid polymer electrolyte films

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The preparation of P(GMA-co-PMMA)-LiTf based solid polymer electrolyte was carried out to study the effect of lithium ions on the room temperature conductivity. The copolymer of (GM-co-MM) was synthesized by photopolymerization method. The films were prepared with different percentage by weight of LiTf. The samples were tested using impedance spectroscopy, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The highest ionic conductivity achieved was 1.2×10-4S cm-1 for the sample prepared with 30% of LiTf at 393k. The decomposition temperature increases with the increase in the salt content. This thermal property influences the enhancement of the conductivity value. The morphology of the samples shows that the number of pores on polymer system reduces by adding salt. In conclusion, the addition of LiCF3SO3 improves the ionic conductivity of P(GMA-co-MMA)(90/10) solid polymer electrolyte from 1.73×10-12 S cm-1 to 1.4×10-6 S cm-1 for the sample prepared with of 0 and 30% of LiTf at room temperature, respectively. The conductivity was improved about 6 magnitude after the addition of 30 wt. % LiTf salt to the polymer host.

Original languageEnglish
Title of host publication8th Asian-Australasian Conference on Composite Materials 2012, ACCM 2012 - Composites: Enabling Tomorrow's Industry Today
Pages679-684
Number of pages6
Volume1
Publication statusPublished - 2012
Event8th Asian-Australasian Conference on Composite Materials 2012 - Composites: Enabling Tomorrow's Industry Today, ACCM 2012 - Kuala Lumpur
Duration: 6 Nov 20128 Nov 2012

Other

Other8th Asian-Australasian Conference on Composite Materials 2012 - Composites: Enabling Tomorrow's Industry Today, ACCM 2012
CityKuala Lumpur
Period6/11/128/11/12

Fingerprint

Methacrylates
Lithium
Electrolytes
Polymers
Salts
Ionic conductivity
Photopolymerization
Polymethyl Methacrylate
Temperature
Thermogravimetric analysis
Thermodynamic properties
Copolymers
Spectroscopy
Ions
Decomposition
Scanning electron microscopy
glycidyl methacrylate

Keywords

  • Glycidyl methacrylate (GMA)
  • Ionic conductivity
  • Lithium Triflate (LiCFSO)
  • Methyl methacrylate (MMA)
  • Solid polymer electrolyte

ASJC Scopus subject areas

  • Ceramics and Composites

Cite this

Imperiykra, M., Ahmad, A., & Abu Hanifah, S. (2012). Conductivity and structural studies of pol(glycidyl methacrylate(GMA) -methyl methacrylate(MMA) -lithium triflate (LiCF3SO3) solid polymer electrolyte films. In 8th Asian-Australasian Conference on Composite Materials 2012, ACCM 2012 - Composites: Enabling Tomorrow's Industry Today (Vol. 1, pp. 679-684)

Conductivity and structural studies of pol(glycidyl methacrylate(GMA) -methyl methacrylate(MMA) -lithium triflate (LiCF3SO3) solid polymer electrolyte films. / Imperiykra, M.; Ahmad, Azizan; Abu Hanifah, Sharina.

8th Asian-Australasian Conference on Composite Materials 2012, ACCM 2012 - Composites: Enabling Tomorrow's Industry Today. Vol. 1 2012. p. 679-684.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Imperiykra, M, Ahmad, A & Abu Hanifah, S 2012, Conductivity and structural studies of pol(glycidyl methacrylate(GMA) -methyl methacrylate(MMA) -lithium triflate (LiCF3SO3) solid polymer electrolyte films. in 8th Asian-Australasian Conference on Composite Materials 2012, ACCM 2012 - Composites: Enabling Tomorrow's Industry Today. vol. 1, pp. 679-684, 8th Asian-Australasian Conference on Composite Materials 2012 - Composites: Enabling Tomorrow's Industry Today, ACCM 2012, Kuala Lumpur, 6/11/12.
Imperiykra M, Ahmad A, Abu Hanifah S. Conductivity and structural studies of pol(glycidyl methacrylate(GMA) -methyl methacrylate(MMA) -lithium triflate (LiCF3SO3) solid polymer electrolyte films. In 8th Asian-Australasian Conference on Composite Materials 2012, ACCM 2012 - Composites: Enabling Tomorrow's Industry Today. Vol. 1. 2012. p. 679-684
Imperiykra, M. ; Ahmad, Azizan ; Abu Hanifah, Sharina. / Conductivity and structural studies of pol(glycidyl methacrylate(GMA) -methyl methacrylate(MMA) -lithium triflate (LiCF3SO3) solid polymer electrolyte films. 8th Asian-Australasian Conference on Composite Materials 2012, ACCM 2012 - Composites: Enabling Tomorrow's Industry Today. Vol. 1 2012. pp. 679-684
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abstract = "The preparation of P(GMA-co-PMMA)-LiTf based solid polymer electrolyte was carried out to study the effect of lithium ions on the room temperature conductivity. The copolymer of (GM-co-MM) was synthesized by photopolymerization method. The films were prepared with different percentage by weight of LiTf. The samples were tested using impedance spectroscopy, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The highest ionic conductivity achieved was 1.2×10-4S cm-1 for the sample prepared with 30{\%} of LiTf at 393k. The decomposition temperature increases with the increase in the salt content. This thermal property influences the enhancement of the conductivity value. The morphology of the samples shows that the number of pores on polymer system reduces by adding salt. In conclusion, the addition of LiCF3SO3 improves the ionic conductivity of P(GMA-co-MMA)(90/10) solid polymer electrolyte from 1.73×10-12 S cm-1 to 1.4×10-6 S cm-1 for the sample prepared with of 0 and 30{\%} of LiTf at room temperature, respectively. The conductivity was improved about 6 magnitude after the addition of 30 wt. {\%} LiTf salt to the polymer host.",
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AB - The preparation of P(GMA-co-PMMA)-LiTf based solid polymer electrolyte was carried out to study the effect of lithium ions on the room temperature conductivity. The copolymer of (GM-co-MM) was synthesized by photopolymerization method. The films were prepared with different percentage by weight of LiTf. The samples were tested using impedance spectroscopy, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The highest ionic conductivity achieved was 1.2×10-4S cm-1 for the sample prepared with 30% of LiTf at 393k. The decomposition temperature increases with the increase in the salt content. This thermal property influences the enhancement of the conductivity value. The morphology of the samples shows that the number of pores on polymer system reduces by adding salt. In conclusion, the addition of LiCF3SO3 improves the ionic conductivity of P(GMA-co-MMA)(90/10) solid polymer electrolyte from 1.73×10-12 S cm-1 to 1.4×10-6 S cm-1 for the sample prepared with of 0 and 30% of LiTf at room temperature, respectively. The conductivity was improved about 6 magnitude after the addition of 30 wt. % LiTf salt to the polymer host.

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