Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11- Tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts

Ameera Aqeela Salleh Huddin, Bohari Mohd. Yamin, Siti Fairus Mohd Yusoff

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Copper complexes have been synthesized with 14-membered macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11- Tetraazacyclotetradeca-7,14-dienium bromide (Me6N4H4)Br2 as ligand having six methyl groups and two double bonds located in diagonal position. These complexes were characterized by microelemental analysis, Fourier Transform Infrared (FTIR) and Ultraviolet-Visible (UV-VIS) spectroscopies. The chemical analysis and spectroscopic data is supported by chemical crystallographic study showed that one of the synthesized copper complex with CuCl2 consists of [Cu(Me6N4H2)] dication, two bromide counter anions and 2 water molecules of crystallisation. Thermogravimetry Analysis (TGA) showed that the complex is stable up to about 200°C before gradually decomposed up to 400°C.

Original languageEnglish
Title of host publication2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium
EditorsZahari Ibrahim, Haja Maideen Kader Maideen, Nazlina Ibrahim, Nurul Huda Abd Karim, Taufik Yusof, Fatimah Abdul Razak, Nurulkamal Maseran, Rozida Mohd Khalid, Noor Baa'yah Ibrahim, Hasidah Mohd. Sidek, Mohd Salmi Md Noorani, Norbert Simon
PublisherAmerican Institute of Physics Inc.
Pages371-374
Number of pages4
ISBN (Electronic)9780735412507
DOIs
Publication statusPublished - 1 Jan 2014
Event2014 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2014 - Selangor, Malaysia
Duration: 9 Apr 201411 Apr 2014

Publication series

NameAIP Conference Proceedings
Volume1614
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Other

Other2014 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2014
CountryMalaysia
CitySelangor
Period9/4/1411/4/14

Fingerprint

bromides
salts
copper
Fourier analysis
thermogravimetry
chemical analysis
counters
crystallization
anions
ligands
water
spectroscopy
molecules

Keywords

  • Copper complexes
  • Macrocyclic
  • Tetraaza

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Huddin, A. A. S., Mohd. Yamin, B., & Mohd Yusoff, S. F. (2014). Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11- Tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts. In Z. Ibrahim, H. M. K. Maideen, N. Ibrahim, N. H. A. Karim, T. Yusof, F. A. Razak, N. Maseran, R. M. Khalid, N. B. Ibrahim, H. M. Sidek, M. S. M. Noorani, ... N. Simon (Eds.), 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium (pp. 371-374). (AIP Conference Proceedings; Vol. 1614). American Institute of Physics Inc.. https://doi.org/10.1063/1.4895225

Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11- Tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts. / Huddin, Ameera Aqeela Salleh; Mohd. Yamin, Bohari; Mohd Yusoff, Siti Fairus.

2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. ed. / Zahari Ibrahim; Haja Maideen Kader Maideen; Nazlina Ibrahim; Nurul Huda Abd Karim; Taufik Yusof; Fatimah Abdul Razak; Nurulkamal Maseran; Rozida Mohd Khalid; Noor Baa'yah Ibrahim; Hasidah Mohd. Sidek; Mohd Salmi Md Noorani; Norbert Simon. American Institute of Physics Inc., 2014. p. 371-374 (AIP Conference Proceedings; Vol. 1614).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Huddin, AAS, Mohd. Yamin, B & Mohd Yusoff, SF 2014, Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11- Tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts. in Z Ibrahim, HMK Maideen, N Ibrahim, NHA Karim, T Yusof, FA Razak, N Maseran, RM Khalid, NB Ibrahim, HM Sidek, MSM Noorani & N Simon (eds), 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. AIP Conference Proceedings, vol. 1614, American Institute of Physics Inc., pp. 371-374, 2014 Postgraduate Colloquium of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology, UKM FST 2014, Selangor, Malaysia, 9/4/14. https://doi.org/10.1063/1.4895225
Huddin AAS, Mohd. Yamin B, Mohd Yusoff SF. Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11- Tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts. In Ibrahim Z, Maideen HMK, Ibrahim N, Karim NHA, Yusof T, Razak FA, Maseran N, Khalid RM, Ibrahim NB, Sidek HM, Noorani MSM, Simon N, editors, 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. American Institute of Physics Inc. 2014. p. 371-374. (AIP Conference Proceedings). https://doi.org/10.1063/1.4895225
Huddin, Ameera Aqeela Salleh ; Mohd. Yamin, Bohari ; Mohd Yusoff, Siti Fairus. / Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11- Tetraazacyclotetradeca-7,14-dienium Bromide with Copper Salts. 2014 UKM FST Postgraduate Colloquium - Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. editor / Zahari Ibrahim ; Haja Maideen Kader Maideen ; Nazlina Ibrahim ; Nurul Huda Abd Karim ; Taufik Yusof ; Fatimah Abdul Razak ; Nurulkamal Maseran ; Rozida Mohd Khalid ; Noor Baa'yah Ibrahim ; Hasidah Mohd. Sidek ; Mohd Salmi Md Noorani ; Norbert Simon. American Institute of Physics Inc., 2014. pp. 371-374 (AIP Conference Proceedings).
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