Chloro(1-isopropylidene-4-methyl-3-thiosemicarbazidato-κ 2N3,S)dimethyltin(IV)

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Abstract

In the title compound, [Sn(CH3)2(C5H 10N3S)Cl], the 1-isopropylidene-4-methyl-3- thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is stabilized by intramolecular C-H⋯N and intermolecular N-H⋯S hydrogen bonds. The latter link the molecules into dimers.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number11
DOIs
Publication statusPublished - 1 Nov 2005

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Molecular Structure
Hydrogen
Ligands
Atoms
Dimers
Molecular structure
atoms
Hydrogen bonds
molecular structure
dimers
hydrogen bonds
ligands
Molecules
configurations
molecules
propylene
dimethyltin

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

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title = "Chloro(1-isopropylidene-4-methyl-3-thiosemicarbazidato-κ 2N3,S)dimethyltin(IV)",
abstract = "In the title compound, [Sn(CH3)2(C5H 10N3S)Cl], the 1-isopropylidene-4-methyl-3- thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is stabilized by intramolecular C-H⋯N and intermolecular N-H⋯S hydrogen bonds. The latter link the molecules into dimers.",
author = "Swesi, {Abdurazaq T.} and {Abdul Aziz}, {Yang Farina} and {Mohd. Yamin}, Bohari",
year = "2005",
month = "11",
day = "1",
doi = "10.1107/S1600536805034136",
language = "English",
volume = "61",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "11",

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T1 - Chloro(1-isopropylidene-4-methyl-3-thiosemicarbazidato-κ 2N3,S)dimethyltin(IV)

AU - Swesi, Abdurazaq T.

AU - Abdul Aziz, Yang Farina

AU - Mohd. Yamin, Bohari

PY - 2005/11/1

Y1 - 2005/11/1

N2 - In the title compound, [Sn(CH3)2(C5H 10N3S)Cl], the 1-isopropylidene-4-methyl-3- thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is stabilized by intramolecular C-H⋯N and intermolecular N-H⋯S hydrogen bonds. The latter link the molecules into dimers.

AB - In the title compound, [Sn(CH3)2(C5H 10N3S)Cl], the 1-isopropylidene-4-methyl-3- thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is stabilized by intramolecular C-H⋯N and intermolecular N-H⋯S hydrogen bonds. The latter link the molecules into dimers.

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U2 - 10.1107/S1600536805034136

DO - 10.1107/S1600536805034136

M3 - Article

VL - 61

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 11

ER -