Catena-poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1, 7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido]

Bohari Mohd. Yamin, Wafiuddin Ismail, Jean Claude Daran

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In the title compound, [Cu2Cl4(C16H 32N4)]n, the central CuII anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu - Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [101̄]. The geometry of the Cu-macrocyclic complex is distorted octahedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central CuII atom. The tetrachloridocuprate anion adopts a distorted tetrahedral geometry. In the crystal, the chain is stabilized by intra- and intermolecular N - H⋯Cl hydrogen bonds.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number7
DOIs
Publication statusPublished - Jul 2012

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dienes
Anions
Copper
Negative ions
anions
copper
Atoms
atoms
Geometry
geometry
Cations
Hydrogen bonds
Positive ions
hydrogen bonds
cations
Crystals
crystals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Catena-poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1, 7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido]. / Mohd. Yamin, Bohari; Ismail, Wafiuddin; Daran, Jean Claude.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 7, 07.2012.

Research output: Contribution to journalArticle

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title = "Catena-poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1, 7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido]",
abstract = "In the title compound, [Cu2Cl4(C16H 32N4)]n, the central CuII anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu - Cl distances of 3.008 (3) and 3.220 (3) {\AA}, respectively, forming a chain parallel to [101̄]. The geometry of the Cu-macrocyclic complex is distorted octahedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central CuII atom. The tetrachloridocuprate anion adopts a distorted tetrahedral geometry. In the crystal, the chain is stabilized by intra- and intermolecular N - H⋯Cl hydrogen bonds.",
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AB - In the title compound, [Cu2Cl4(C16H 32N4)]n, the central CuII anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu - Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [101̄]. The geometry of the Cu-macrocyclic complex is distorted octahedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central CuII atom. The tetrachloridocuprate anion adopts a distorted tetrahedral geometry. In the crystal, the chain is stabilized by intra- and intermolecular N - H⋯Cl hydrogen bonds.

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