Bis(N-sec-butyl-N-n-propyldithio-carbamato-κ2S,S′) (1,10-phenanthroline-κ2N,N′)zinc(II)

Amna Salem Alzaalouk, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir, Seik Weng Ng, Edward R T Tiekink

    Research output: Contribution to journalArticle

    Abstract

    Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Zn(C8H16NS2) 2(C12H8N2)]. The N2S 4 donor set about Zn is defined by two symmetrically chelating dithiocarbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octahedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetrameric supramolecular aggregates mediated by C-H⋯S interactions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5).

    Original languageEnglish
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume66
    Issue number9
    DOIs
    Publication statusPublished - Sep 2010

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    Zinc
    zinc
    Ligands
    ligands
    disorders
    Chelation
    Crystals
    Molecules
    Geometry
    geometry
    crystals
    1,10-phenanthroline
    molecules
    interactions

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Materials Science(all)
    • Chemistry(all)

    Cite this

    Bis(N-sec-butyl-N-n-propyldithio-carbamato-κ2S,S′) (1,10-phenanthroline-κ2N,N′)zinc(II). / Alzaalouk, Amna Salem; Baba, Ibrahim; Mohamed Tahir, Mohamed Ibrahim; Ng, Seik Weng; Tiekink, Edward R T.

    In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 9, 09.2010.

    Research output: Contribution to journalArticle

    Alzaalouk, Amna Salem ; Baba, Ibrahim ; Mohamed Tahir, Mohamed Ibrahim ; Ng, Seik Weng ; Tiekink, Edward R T. / Bis(N-sec-butyl-N-n-propyldithio-carbamato-κ2S,S′) (1,10-phenanthroline-κ2N,N′)zinc(II). In: Acta Crystallographica Section E: Structure Reports Online. 2010 ; Vol. 66, No. 9.
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    abstract = "Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Zn(C8H16NS2) 2(C12H8N2)]. The N2S 4 donor set about Zn is defined by two symmetrically chelating dithiocarbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octahedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetrameric supramolecular aggregates mediated by C-H⋯S interactions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5).",
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    AU - Alzaalouk, Amna Salem

    AU - Baba, Ibrahim

    AU - Mohamed Tahir, Mohamed Ibrahim

    AU - Ng, Seik Weng

    AU - Tiekink, Edward R T

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