Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido- κ2N,O}copper(II)

M. Sukeri M Yusof, Maisara A. Kadir, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the centrosymmetric mononuclear title complex, [Cu(C18H 20N2O2)2], the CuII atom is four-coordinated in a trans-CuN2O2 square-planar geometry with the N - Cu - O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methylbenzene and 2,4-dimethylbenzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intramolecular C - H⋯N hydrogen bond occurs.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number7
DOIs
Publication statusPublished - Jul 2012

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Copper
Carbon
chelates
copper
Xylenes
rings
Dihedral angle
Hydrogen bonds
carbon
Atoms
Geometry
dihedral angle
fragments
hydrogen bonds
geometry
atoms

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

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Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido- κ2N,O}copper(II). / Yusof, M. Sukeri M; Kadir, Maisara A.; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 7, 07.2012.

Research output: Contribution to journalArticle

Yusof, M. Sukeri M ; Kadir, Maisara A. ; Mohd. Yamin, Bohari. / Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido- κ2N,O}copper(II). In: Acta Crystallographica Section E: Structure Reports Online. 2012 ; Vol. 68, No. 7.
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abstract = "In the centrosymmetric mononuclear title complex, [Cu(C18H 20N2O2)2], the CuII atom is four-coordinated in a trans-CuN2O2 square-planar geometry with the N - Cu - O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methylbenzene and 2,4-dimethylbenzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intramolecular C - H⋯N hydrogen bond occurs.",
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