Bis(N-benzyl-N-isopropyl-dithio-carbamato-κS)di-n-butyl-tin(IV)

Ibrahim Baba, Nor Syaidatul Akmal, Normah Awang, Seik Weng Ng

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The Sn atom in the title compound, [Sn(C4H9)2(C11H14NS2)2], exists in a tetra-hedral C2S2Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C2Sn angles range from 129.0 (2) to 136.9 (2)°, the covalent Sn - S lengths from 2.529 (1) to 2.544 (1) Å, and the dative Sn←S lengths from 2.831 (1) to 3.042 (1) Å in the five independent mol-ecules comprising the asymmetric unit. Two of the butyl groups were modelled over two positions of equal occupancy. All butyl groups were refined with distance restraints.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number5
DOIs
Publication statusPublished - 2009

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Tin
tin
Atoms
Geometry
geometry
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proximity

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Bis(N-benzyl-N-isopropyl-dithio-carbamato-κS)di-n-butyl-tin(IV). / Baba, Ibrahim; Akmal, Nor Syaidatul; Awang, Normah; Ng, Seik Weng.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 5, 2009.

Research output: Contribution to journalArticle

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