Bis[di-2-pyridyl(hydroxy)methanolato-κ 3O,N,N′]-iron(I) tetrafluoroborate trihydrate

Djulia Onggo, Aminah Mimin, Bohari Mohd. Yamin, Seik Weng Ng

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Fe(C11H 9-O2N2)2]BF 4·3H2O, contains two independent bis[di-2-pyridyl(hydroxy)methanolato-κ3O,N,N′)]iron(III) cations, with the Fe atom occupying a special position of 1̄ symmetry in each case; the Fe atom is O,N,N′-chelated by the anionic ligands in an octahedral geometry. The cation, the disordered BF4 - counter-ion and the uncoordinated water molecules interact via hydrogen bonds to form a sheet motif.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number2
DOIs
Publication statusPublished - Feb 2005

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Cations
Iron
Positive ions
iron
cations
Atoms
Radiation counters
atoms
Hydrogen
Hydrogen bonds
counters
Crystal structure
Ligands
Ions
hydrogen bonds
ligands
crystal structure
Molecules
Geometry
Water

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Bis[di-2-pyridyl(hydroxy)methanolato-κ 3O,N,N′]-iron(I) tetrafluoroborate trihydrate. / Onggo, Djulia; Mimin, Aminah; Mohd. Yamin, Bohari; Ng, Seik Weng.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 2, 02.2005.

Research output: Contribution to journalArticle

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AU - Ng, Seik Weng

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