Bis(2,3-dibromo-6,7,9,10,12,13,15,16-octahydro-5,8,11,14, 17-pentaoxabenzocyclo-pentadecene) hydroxonium tribromide

M. Idiris Saleh, Eny Kusrini, Nurziana Ngah, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

In the title compound, 2C14H18O5Br 2·OH3 +·Br3 -, the two 15-crown-5 macrocylic rings are linked by an oxonium cation via O-H⋯O hydrogen bonds, forming a positively charged unsymmetrical sandwich-like compound with a tribromide counter-anion. The conformations of the two crown-5 fragments have gauche C-C and and C-O linkages.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number4
DOIs
Publication statusPublished - 1 Apr 2006

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Crowns
linkages
Anions
Conformations
Cations
Hydrogen
Hydrogen bonds
counters
Negative ions
Positive ions
fragments
hydrogen bonds
anions
cations
rings
15-crown-5
hydronium ion

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Bis(2,3-dibromo-6,7,9,10,12,13,15,16-octahydro-5,8,11,14, 17-pentaoxabenzocyclo-pentadecene) hydroxonium tribromide. / Idiris Saleh, M.; Kusrini, Eny; Ngah, Nurziana; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 62, No. 4, 01.04.2006.

Research output: Contribution to journalArticle

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AU - Idiris Saleh, M.

AU - Kusrini, Eny

AU - Ngah, Nurziana

AU - Mohd. Yamin, Bohari

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N2 - In the title compound, 2C14H18O5Br 2·OH3 +·Br3 -, the two 15-crown-5 macrocylic rings are linked by an oxonium cation via O-H⋯O hydrogen bonds, forming a positively charged unsymmetrical sandwich-like compound with a tribromide counter-anion. The conformations of the two crown-5 fragments have gauche C-C and and C-O linkages.

AB - In the title compound, 2C14H18O5Br 2·OH3 +·Br3 -, the two 15-crown-5 macrocylic rings are linked by an oxonium cation via O-H⋯O hydrogen bonds, forming a positively charged unsymmetrical sandwich-like compound with a tribromide counter-anion. The conformations of the two crown-5 fragments have gauche C-C and and C-O linkages.

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