Bis[μ-1-(2-pyridyl-κN)ethanone 4-phenylthio-semicarbazonato-κ2N 1,S]bis[iodomercury(II)]

Bohari Mohd. Yamin, M. Sukeri M Yusof

Research output: Contribution to journalArticle

Abstract

The title compound, [Hg2(C14H13N 4S)2I2], is a dimeric complex of mercury(II) with the N,N,S-tridentate electron-donor Schiff base ligand and lies on a crystallographic twofold axis. The two Hg atoms are linked by two bridging S atoms, forming a rectangular base with Hg-S bond lengths of 2.6490 (12) and 2.6173 (11) Å. The two tridentate ligands are almost perpendicular to the base, resulting in an open box-like structure. The geometry of the Hg atoms is between trigonal bipyramidal and square pyramidal, but closer to the latter.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number3
DOIs
Publication statusPublished - Mar 2005

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Ligands
Atoms
Schiff Bases
Mercury
atoms
ligands
Bond length
Electrons
imines
boxes
Geometry
geometry
electrons

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Bis[μ-1-(2-pyridyl-κN)ethanone 4-phenylthio-semicarbazonato-κ2N 1,S]bis[iodomercury(II)]. / Mohd. Yamin, Bohari; Yusof, M. Sukeri M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 3, 03.2005.

Research output: Contribution to journalArticle

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