(Bipyridine-κ2N,N′)chlorido[N-(2-hydroxyethyl) -N-isopropyldithiocarbamato-κ2S,S′]zinc(II)

Fatin Allia Mohamad, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir, Edward R T Tiekink

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    The ZnII atom in the title compound, [Zn(C6H 12NOS2)Cl(C10H8N2)], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN2S 2 donor set defines a distorted square-pyramidal coordination geometry. Helical supramolecular chains sustained by O - H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C - H⋯O, C - H⋯S and C - H⋯Cl interactions.

    Original languageEnglish
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume68
    Issue number7
    DOIs
    Publication statusPublished - Jul 2012

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    Zinc
    zinc
    Ligands
    Atoms
    ligands
    Chelation
    atoms
    Hydrogen bonds
    hydrogen bonds
    Crystals
    Geometry
    geometry
    crystals
    interactions

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Materials Science(all)
    • Chemistry(all)

    Cite this

    (Bipyridine-κ2N,N′)chlorido[N-(2-hydroxyethyl) -N-isopropyldithiocarbamato-κ2S,S′]zinc(II). / Mohamad, Fatin Allia; Baba, Ibrahim; Mohamed Tahir, Mohamed Ibrahim; Tiekink, Edward R T.

    In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 7, 07.2012.

    Research output: Contribution to journalArticle

    Mohamad, Fatin Allia ; Baba, Ibrahim ; Mohamed Tahir, Mohamed Ibrahim ; Tiekink, Edward R T. / (Bipyridine-κ2N,N′)chlorido[N-(2-hydroxyethyl) -N-isopropyldithiocarbamato-κ2S,S′]zinc(II). In: Acta Crystallographica Section E: Structure Reports Online. 2012 ; Vol. 68, No. 7.
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    abstract = "The ZnII atom in the title compound, [Zn(C6H 12NOS2)Cl(C10H8N2)], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN2S 2 donor set defines a distorted square-pyramidal coordination geometry. Helical supramolecular chains sustained by O - H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C - H⋯O, C - H⋯S and C - H⋯Cl interactions.",
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    T1 - (Bipyridine-κ2N,N′)chlorido[N-(2-hydroxyethyl) -N-isopropyldithiocarbamato-κ2S,S′]zinc(II)

    AU - Mohamad, Fatin Allia

    AU - Baba, Ibrahim

    AU - Mohamed Tahir, Mohamed Ibrahim

    AU - Tiekink, Edward R T

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    AB - The ZnII atom in the title compound, [Zn(C6H 12NOS2)Cl(C10H8N2)], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN2S 2 donor set defines a distorted square-pyramidal coordination geometry. Helical supramolecular chains sustained by O - H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C - H⋯O, C - H⋯S and C - H⋯Cl interactions.

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