Application of pulse radiolysis to the study of the chemistry of radical anions

Abdul Amir H. Kadhum, J. R. Langan, G. A. Salamon, P. P. Edwards

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The application of pulse radiolysis to the measurement of rates of reaction of aromatic and olefinic radical anions in organic solvents is discussed, emphasis being placed on the problem of reaction of the radical anion with the radiolytically-generated-counter ion. Some previous experiments of the authors that utilised tetrahydridoaluminate salts to scavenge the counter ion are reviewed. Some new data on the rates of electron transfer from aromatic-radical anions to some substituted styrenes are presented and experiments aimed at using organic amides as solvents for these studies are described.

Original languageEnglish
Pages (from-to)319-327
Number of pages9
JournalJournal of Radioanalytical and Nuclear Chemistry Articles
Volume101
Issue number2
DOIs
Publication statusPublished - Oct 1986
Externally publishedYes

Fingerprint

Pulse Radiolysis
Radiolysis
Anions
Negative ions
Radiation counters
Styrenes
Ions
Amides
Organic solvents
Styrene
Salts
Experiments
Electrons

ASJC Scopus subject areas

  • Nuclear Energy and Engineering
  • Inorganic Chemistry
  • Analytical Chemistry

Cite this

Application of pulse radiolysis to the study of the chemistry of radical anions. / Kadhum, Abdul Amir H.; Langan, J. R.; Salamon, G. A.; Edwards, P. P.

In: Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 101, No. 2, 10.1986, p. 319-327.

Research output: Contribution to journalArticle

Kadhum, Abdul Amir H. ; Langan, J. R. ; Salamon, G. A. ; Edwards, P. P. / Application of pulse radiolysis to the study of the chemistry of radical anions. In: Journal of Radioanalytical and Nuclear Chemistry Articles. 1986 ; Vol. 101, No. 2. pp. 319-327.
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