An electrochemical procedure coupled with a Schiff base method; Application to electroorganic synthesis of New Nitrogen-containing heterocycles

Bahram Dowlati, Mohamed Rozali Othman

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The synthesis of Nitrogen-containing heterocycles has been achieved using chemical and electrochemical methods, respectively. The direct chemical synthesis of nucleophiles proceeds through the Schiff base chemical reaction. This procedure offers an alternate reaction between dicarbonyl compounds and diamines leads to the formation of products. The results indicate that the Schiff base chemical method for synthesis of the product has successfully performed in excellent overall yield. In the electrochemical step, a series of Nitrogen-containing compounds were electrosynthesized. Various parameters such as the applied potential, pH of the electrolytic solution, cell configuration and also purification techniques, were carried out to optimize the yields of corresponding products. New Nitrogen-containing heterocycle derivatives were synthesized using an electrochemical procedure coupled with a Schiff base as a facile, efficient and practical method. The products have been characterized after purification by IR, 1H NMR, 13C NMR and ESI-MS 2.

Original languageEnglish
Title of host publicationAIP Conference Proceedings
Pages795-800
Number of pages6
Volume1571
DOIs
Publication statusPublished - 2013
Event2013 UKM Faculty of Science and Technology Post-Graduate Colloquium - Selangor
Duration: 3 Jul 20134 Jul 2013

Other

Other2013 UKM Faculty of Science and Technology Post-Graduate Colloquium
CitySelangor
Period3/7/134/7/13

Fingerprint

imines
nitrogen
synthesis
products
purification
nitrogen compounds
nuclear magnetic resonance
nucleophiles
diamines
configurations
cells

Keywords

  • Electrochemical oxidation
  • Electroorganic synthesis
  • Nitrogen-containing compounds
  • Schiff base reaction

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

An electrochemical procedure coupled with a Schiff base method; Application to electroorganic synthesis of New Nitrogen-containing heterocycles. / Dowlati, Bahram; Othman, Mohamed Rozali.

AIP Conference Proceedings. Vol. 1571 2013. p. 795-800.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Dowlati, B & Othman, MR 2013, An electrochemical procedure coupled with a Schiff base method; Application to electroorganic synthesis of New Nitrogen-containing heterocycles. in AIP Conference Proceedings. vol. 1571, pp. 795-800, 2013 UKM Faculty of Science and Technology Post-Graduate Colloquium, Selangor, 3/7/13. https://doi.org/10.1063/1.4858752
Dowlati, Bahram ; Othman, Mohamed Rozali. / An electrochemical procedure coupled with a Schiff base method; Application to electroorganic synthesis of New Nitrogen-containing heterocycles. AIP Conference Proceedings. Vol. 1571 2013. pp. 795-800
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