6,6′-Dimeth-oxy-2,2′-[(E,E′)-(4-chloro-m-phenyl-ene) bis-(nitrilo-methyl-idyne)]diphenol

Bohari Mohd. Yamin, Siti Najihah A Bakar, Karimah Kassim, Hadariah Bahron

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The title compound, C22H19ClN2O4, has the appearance of a warped butterfly. One 2-hydr-oxy-3-methoxy-benzyl-idene-amino fragment is planar [with a maximum deviation of 0.056 (3) Å] and forms a dihedral angle of 9.85 (9)° with the central benzene ring. The other fragment is not planar; however, the methoxy-phenol group is planar [with the maximum deviation of 0.033 (2) Å] and makes a dihedral angle of 41.7 (3)° with the central benzene ring. The mol-ecule is stabilized by intra-molecular O- H⋯N hydrogen bonding. The crystal structure is stabilized by weak inter-molecular C- H⋯O hydrogen bonding and C- H⋯π inter-actions.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number10
DOIs
Publication statusPublished - 2009

Fingerprint

Dihedral angle
Benzene
dihedral angle
Hydrogen bonds
benzene
fragments
deviation
rings
hydrogen
Phenol
phenols
Phenols
Crystal structure
crystal structure

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

6,6′-Dimeth-oxy-2,2′-[(E,E′)-(4-chloro-m-phenyl-ene) bis-(nitrilo-methyl-idyne)]diphenol. / Mohd. Yamin, Bohari; Bakar, Siti Najihah A; Kassim, Karimah; Bahron, Hadariah.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 10, 2009.

Research output: Contribution to journalArticle

Mohd. Yamin, Bohari ; Bakar, Siti Najihah A ; Kassim, Karimah ; Bahron, Hadariah. / 6,6′-Dimeth-oxy-2,2′-[(E,E′)-(4-chloro-m-phenyl-ene) bis-(nitrilo-methyl-idyne)]diphenol. In: Acta Crystallographica Section E: Structure Reports Online. 2009 ; Vol. 65, No. 10.
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abstract = "The title compound, C22H19ClN2O4, has the appearance of a warped butterfly. One 2-hydr-oxy-3-methoxy-benzyl-idene-amino fragment is planar [with a maximum deviation of 0.056 (3) {\AA}] and forms a dihedral angle of 9.85 (9)° with the central benzene ring. The other fragment is not planar; however, the methoxy-phenol group is planar [with the maximum deviation of 0.033 (2) {\AA}] and makes a dihedral angle of 41.7 (3)° with the central benzene ring. The mol-ecule is stabilized by intra-molecular O- H⋯N hydrogen bonding. The crystal structure is stabilized by weak inter-molecular C- H⋯O hydrogen bonding and C- H⋯π inter-actions.",
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AU - Kassim, Karimah

AU - Bahron, Hadariah

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