6,6′-Dimeth-oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1, 3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate

Hadariah Bahron, Najihah Abu Bakar, Bohari Mohd. Yamin, M. Sukeri M Yusof

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the title compound, C25H26N2O 4·CHCl3, the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N hydrogen bonds. In the crystal, an inter-molecular C-H⋯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by π-π stacking inter-actions [centroid-centroid distances = 3.739 (3)-3.776 (3) Å] between the benzene rings of centrosymmetrically related mol-ecules.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number4
DOIs
Publication statusPublished - Apr 2012

Fingerprint

Benzene
Hydrogen bonds
centroids
Crystals
rings
Dihedral angle
Phenol
benzene
hydrogen bonds
Phenols
Conformations
phenols
crystals
dihedral angle
fragments

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

6,6′-Dimeth-oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1, 3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate. / Bahron, Hadariah; Bakar, Najihah Abu; Mohd. Yamin, Bohari; Yusof, M. Sukeri M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 4, 04.2012.

Research output: Contribution to journalArticle

@article{3ca07fcdf1194258bd567e1cedd11d8f,
title = "6,6′-Dimeth-oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1, 3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate",
abstract = "In the title compound, C25H26N2O 4·CHCl3, the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N hydrogen bonds. In the crystal, an inter-molecular C-H⋯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by π-π stacking inter-actions [centroid-centroid distances = 3.739 (3)-3.776 (3) {\AA}] between the benzene rings of centrosymmetrically related mol-ecules.",
author = "Hadariah Bahron and Bakar, {Najihah Abu} and {Mohd. Yamin}, Bohari and Yusof, {M. Sukeri M}",
year = "2012",
month = "4",
doi = "10.1107/S1600536812011531",
language = "English",
volume = "68",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "4",

}

TY - JOUR

T1 - 6,6′-Dimeth-oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1, 3-phenyl-ene)bis-(nitrilo-methanylyl-idene)]diphenol chloro-form monosolvate

AU - Bahron, Hadariah

AU - Bakar, Najihah Abu

AU - Mohd. Yamin, Bohari

AU - Yusof, M. Sukeri M

PY - 2012/4

Y1 - 2012/4

N2 - In the title compound, C25H26N2O 4·CHCl3, the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N hydrogen bonds. In the crystal, an inter-molecular C-H⋯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by π-π stacking inter-actions [centroid-centroid distances = 3.739 (3)-3.776 (3) Å] between the benzene rings of centrosymmetrically related mol-ecules.

AB - In the title compound, C25H26N2O 4·CHCl3, the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N hydrogen bonds. In the crystal, an inter-molecular C-H⋯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The crystal packing is further stabilized by π-π stacking inter-actions [centroid-centroid distances = 3.739 (3)-3.776 (3) Å] between the benzene rings of centrosymmetrically related mol-ecules.

UR - http://www.scopus.com/inward/record.url?scp=84860307469&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84860307469&partnerID=8YFLogxK

U2 - 10.1107/S1600536812011531

DO - 10.1107/S1600536812011531

M3 - Article

C2 - 22606118

AN - SCOPUS:84860307469

VL - 68

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 4

ER -