(4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato] -nitrosylmolybdenum(I) dichloromethane monosolvate

Mohammad Kassim, Jon A. McCleverty

Research output: Contribution to journalArticle

Abstract

In the title compound, [Mo(C15H22BN 6)Cl(NO)(C9H13N)]·CH2Cl 2, the MoI atom adopts a distorted MoClN5 octa-hedral geometry with the hydro-tris-(3,5-dimethylpyrazolyl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the MoI atom and an intra-molecular C - H⋯Cl hydrogen bond helps to stabilize the configuration of the complex molecule. The packing is stabilized by an inter-molecular C - H⋯Cl hydrogen bond involving the complex molecule and the CH2Cl2 solvent molecule.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number12
DOIs
Publication statusPublished - Dec 2010

Fingerprint

Methylene Chloride
Dichloromethane
Molecules
Anions
Hydrogen bonds
Negative ions
hydrogen bonds
anions
molecules
Atoms
Borates
borates
complement
atoms
Cations
Chlorides
Positive ions
chlorides
Ligands
cations

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

@article{ad12650e6a2c4a948c929f035bff4fee,
title = "(4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato] -nitrosylmolybdenum(I) dichloromethane monosolvate",
abstract = "In the title compound, [Mo(C15H22BN 6)Cl(NO)(C9H13N)]·CH2Cl 2, the MoI atom adopts a distorted MoClN5 octa-hedral geometry with the hydro-tris-(3,5-dimethylpyrazolyl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the MoI atom and an intra-molecular C - H⋯Cl hydrogen bond helps to stabilize the configuration of the complex molecule. The packing is stabilized by an inter-molecular C - H⋯Cl hydrogen bond involving the complex molecule and the CH2Cl2 solvent molecule.",
author = "Mohammad Kassim and McCleverty, {Jon A.}",
year = "2010",
month = "12",
doi = "10.1107/S1600536810048233",
language = "English",
volume = "66",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "12",

}

TY - JOUR

T1 - (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato] -nitrosylmolybdenum(I) dichloromethane monosolvate

AU - Kassim, Mohammad

AU - McCleverty, Jon A.

PY - 2010/12

Y1 - 2010/12

N2 - In the title compound, [Mo(C15H22BN 6)Cl(NO)(C9H13N)]·CH2Cl 2, the MoI atom adopts a distorted MoClN5 octa-hedral geometry with the hydro-tris-(3,5-dimethylpyrazolyl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the MoI atom and an intra-molecular C - H⋯Cl hydrogen bond helps to stabilize the configuration of the complex molecule. The packing is stabilized by an inter-molecular C - H⋯Cl hydrogen bond involving the complex molecule and the CH2Cl2 solvent molecule.

AB - In the title compound, [Mo(C15H22BN 6)Cl(NO)(C9H13N)]·CH2Cl 2, the MoI atom adopts a distorted MoClN5 octa-hedral geometry with the hydro-tris-(3,5-dimethylpyrazolyl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the MoI atom and an intra-molecular C - H⋯Cl hydrogen bond helps to stabilize the configuration of the complex molecule. The packing is stabilized by an inter-molecular C - H⋯Cl hydrogen bond involving the complex molecule and the CH2Cl2 solvent molecule.

UR - http://www.scopus.com/inward/record.url?scp=78650145253&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78650145253&partnerID=8YFLogxK

U2 - 10.1107/S1600536810048233

DO - 10.1107/S1600536810048233

M3 - Article

C2 - 21589350

AN - SCOPUS:78650145253

VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 12

ER -