(4-fluorophenyl)thiourea-1,10-phenanthroline (1/1)

Research output: Contribution to journalArticle

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Abstract

Refluxing a mixture of 1,10-phenanthroline, (4-fluorophenyl)thiourea and cadmium(II) chloride did not produce the expected mixed-ligand complex but formed a co-crystal of the two ligands, C12H8N 2·C7H7FN2S. The asymmetric unit consists of two pairs of the co-crystal molecules. In each (4-fluorophenyl)thiourea molecule, the planes of the N 2CS thiourea units are almost perpendicular to the corresponding fluorobenzene rings, subtending angles of 76.53 (7) and 85.25 (7)°. In the crystal, N - H⋯N and N - H⋯S hydrogen bonds form inversion dimers from the co-crystal pairs. A weak π-π interaction between the phenanthroline rings [centroid-centroid distance = 3.7430 (15)Å] is also observed.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number9
DOIs
Publication statusPublished - Sep 2013

Fingerprint

Thiourea
Thioureas
thioureas
Crystals
centroids
crystals
Fluorobenzenes
Ligands
Cadmium chloride
ligands
Molecules
Phenanthrolines
rings
Dimers
cadmium
molecules
Hydrogen bonds
chlorides
dimers
inversions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

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(4-fluorophenyl)thiourea-1,10-phenanthroline (1/1). / Mohd. Yamin, Bohari; Salem, Halima F.; Mohd Yusoff, Siti Fairus.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 69, No. 9, 09.2013.

Research output: Contribution to journalArticle

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