{4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate

Hapipah Ali, Nur Ashikin Khamis, W. Jefri Basirun, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number9
DOIs
Publication statusPublished - Sep 2004

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Nickel
Pyridine
pyridines
omega-Chloroacetophenone
Ligands
nickel
Hydrazones
Atoms
hydrazones
ligands
Molecules
atoms
molecules
Crystal structure
crystal structure
pyridine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

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{4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate. / Ali, Hapipah; Khamis, Nur Ashikin; Jefri Basirun, W.; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 9, 09.2004.

Research output: Contribution to journalArticle

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abstract = "The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands.",
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AU - Ali, Hapipah

AU - Khamis, Nur Ashikin

AU - Jefri Basirun, W.

AU - Mohd. Yamin, Bohari

PY - 2004/9

Y1 - 2004/9

N2 - The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands.

AB - The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands.

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