3-[(E)-(4-Chloro-benzyl-idene)amino]-1-phenylthiourea

Nur Nadia Dzulkifli, Yang Farina Abdul Aziz, Bohari Mohd. Yamin, Ibrahim Baba, Edward R T Tiekink

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

In the title compound, C14H12ClN3S, the dihedral angle between the terminal benzene rings is 56.6 (2)°; the benzene rings lie to the same side of the molecule. The major twist in the molecule occurs around the Car - N bond (ar is aromatic) [C - N - C - C = 49.9 (5)°]. The configuration about the N=C bond [1.271 (4) Å] is E. The amine H atoms lie on opposite sides of the molecule with one forming an intra-molecular N - H⋯N(imine) hydrogen bond and an S(5) ring. In the crystal, centrosymmetric dimers are formed via {⋯HNC=S}2 synthons.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number4
DOIs
Publication statusPublished - Apr 2011

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Phenylthiourea
Benzene
Molecules
rings
benzene
molecules
Imines
Dihedral angle
Dimers
imines
Amines
dihedral angle
Hydrogen bonds
amines
Railroad cars
dimers
hydrogen bonds
Atoms
Crystals
configurations

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

3-[(E)-(4-Chloro-benzyl-idene)amino]-1-phenylthiourea. / Dzulkifli, Nur Nadia; Abdul Aziz, Yang Farina; Mohd. Yamin, Bohari; Baba, Ibrahim; Tiekink, Edward R T.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 4, 04.2011.

Research output: Contribution to journalArticle

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AU - Baba, Ibrahim

AU - Tiekink, Edward R T

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