2,4-Dichloro-N-[ethyl(2-hydroxyethyl)carbamothioyl]benzamide

Bohari Mohd. Yamin, Suhaila Sapari, Siti Aishah Hasbullah

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, C12H14Cl2N 2O2S, the molecule adopts a cis conformation with respect to the dichlorobenzoyl group against the thiono group about the C-N bond. However, the dichlorobenzene group and the thiourea moiety are twisted by 75.41(8)°. An intramolecular N-H⋯O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O-H⋯S and O-H⋯O hydrogen bonds link the molecules, forming chains along the b-axis direction.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number1
DOIs
Publication statusPublished - Jan 2014

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Hydrogen bonds
Atoms
Thiourea
Molecules
Thioureas
Hydroxyl Radical
hydrogen bonds
Conformations
thioureas
Crystals
atoms
molecules
crystals
benzamide
Direction compound

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

2,4-Dichloro-N-[ethyl(2-hydroxyethyl)carbamothioyl]benzamide. / Mohd. Yamin, Bohari; Sapari, Suhaila; Hasbullah, Siti Aishah.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 70, No. 1, 01.2014.

Research output: Contribution to journalArticle

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AB - In the title compound, C12H14Cl2N 2O2S, the molecule adopts a cis conformation with respect to the dichlorobenzoyl group against the thiono group about the C-N bond. However, the dichlorobenzene group and the thiourea moiety are twisted by 75.41(8)°. An intramolecular N-H⋯O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O-H⋯S and O-H⋯O hydrogen bonds link the molecules, forming chains along the b-axis direction.

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