(2,2′-Bipyridyl-κ2 N,N′)bis(N-butyl-N- methyldithiocarbamato-κ2 S,S′)cadmium(II)

Nur Amirah Jamaluddin, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir, Edward R T Tiekink

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    The CdII atom in the title compound, [Cd(C6H 12NS2)2(C10H8N 2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N 2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C - H⋯S interactions and these are connected into layers that stack along the c axis via π-π interactions [Cg(pyridyl)⋯Cg(pyridyl) = 3.6587 (13) Å].

    Original languageEnglish
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume67
    Issue number3
    DOIs
    Publication statusPublished - Mar 2011

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    2,2'-Dipyridyl
    Cadmium
    cadmium
    Atoms
    atoms
    Ligands
    interactions
    ligands
    Molecules
    Geometry
    geometry
    molecules
    Direction compound

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Materials Science(all)
    • Chemistry(all)

    Cite this

    (2,2′-Bipyridyl-κ2 N,N′)bis(N-butyl-N- methyldithiocarbamato-κ2 S,S′)cadmium(II). / Jamaluddin, Nur Amirah; Baba, Ibrahim; Mohamed Tahir, Mohamed Ibrahim; Tiekink, Edward R T.

    In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 3, 03.2011.

    Research output: Contribution to journalArticle

    Jamaluddin, Nur Amirah ; Baba, Ibrahim ; Mohamed Tahir, Mohamed Ibrahim ; Tiekink, Edward R T. / (2,2′-Bipyridyl-κ2 N,N′)bis(N-butyl-N- methyldithiocarbamato-κ2 S,S′)cadmium(II). In: Acta Crystallographica Section E: Structure Reports Online. 2011 ; Vol. 67, No. 3.
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    abstract = "The CdII atom in the title compound, [Cd(C6H 12NS2)2(C10H8N 2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N 2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C - H⋯S interactions and these are connected into layers that stack along the c axis via π-π interactions [Cg(pyridyl)⋯Cg(pyridyl) = 3.6587 (13) {\AA}].",
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    AU - Jamaluddin, Nur Amirah

    AU - Baba, Ibrahim

    AU - Mohamed Tahir, Mohamed Ibrahim

    AU - Tiekink, Edward R T

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    AB - The CdII atom in the title compound, [Cd(C6H 12NS2)2(C10H8N 2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2′-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N 2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C - H⋯S interactions and these are connected into layers that stack along the c axis via π-π interactions [Cg(pyridyl)⋯Cg(pyridyl) = 3.6587 (13) Å].

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