(2,2′-Bipyridine-κ2N,N′)bis(N-isopropyl-N- methyldithiocarbamato-κ2S,S′)-cadmium

Nor Asiken Abdul Wahab, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir, Edward R T Tiekink

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    The CdII atom in the title compound, [Cd(C5H 10NS2)2-(C10H8N 2)], exists in an N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H⋯S interactions, leading to linear supramolecular chains along the a axis. The primary connections between these are by π- π stacking interactions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å ]. Overall, the crystal structure may be described as comprising double layers of molecules that stack along the b axis.

    Original languageEnglish
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume67
    Issue number5
    DOIs
    Publication statusPublished - May 2011

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    Chelation
    Prisms
    Cadmium
    cadmium
    Anions
    Negative ions
    Crystal structure
    Ligands
    Atoms
    Crystals
    Molecules
    Geometry
    rings
    centroids
    prisms
    interactions
    anions
    ligands
    crystal structure
    geometry

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Materials Science(all)
    • Chemistry(all)

    Cite this

    (2,2′-Bipyridine-κ2N,N′)bis(N-isopropyl-N- methyldithiocarbamato-κ2S,S′)-cadmium. / Wahab, Nor Asiken Abdul; Baba, Ibrahim; Mohamed Tahir, Mohamed Ibrahim; Tiekink, Edward R T.

    In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 5, 05.2011.

    Research output: Contribution to journalArticle

    Wahab, Nor Asiken Abdul ; Baba, Ibrahim ; Mohamed Tahir, Mohamed Ibrahim ; Tiekink, Edward R T. / (2,2′-Bipyridine-κ2N,N′)bis(N-isopropyl-N- methyldithiocarbamato-κ2S,S′)-cadmium. In: Acta Crystallographica Section E: Structure Reports Online. 2011 ; Vol. 67, No. 5.
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    abstract = "The CdII atom in the title compound, [Cd(C5H 10NS2)2-(C10H8N 2)], exists in an N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H⋯S interactions, leading to linear supramolecular chains along the a axis. The primary connections between these are by π- π stacking interactions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) {\AA} ]. Overall, the crystal structure may be described as comprising double layers of molecules that stack along the b axis.",
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    T1 - (2,2′-Bipyridine-κ2N,N′)bis(N-isopropyl-N- methyldithiocarbamato-κ2S,S′)-cadmium

    AU - Wahab, Nor Asiken Abdul

    AU - Baba, Ibrahim

    AU - Mohamed Tahir, Mohamed Ibrahim

    AU - Tiekink, Edward R T

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    AB - The CdII atom in the title compound, [Cd(C5H 10NS2)2-(C10H8N 2)], exists in an N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C-H⋯S interactions, leading to linear supramolecular chains along the a axis. The primary connections between these are by π- π stacking interactions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å ]. Overall, the crystal structure may be described as comprising double layers of molecules that stack along the b axis.

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