(2,2'-Bipyridine-κ2 N,N')bis-(N-ethyl-N- methyldithiocarbamato-κ2 S,S')zinc(II)

Noorul Aisyah Abdul Ghafar, Ibrahim Baba, Bohari Mohd. Yamin, Seik Weng Ng

Research output: Contribution to journalArticle

Abstract

The complete molecule of the title compound, [Zn(C4H 8NS2)2(C10H8N 2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C - C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number2
DOIs
Publication statusPublished - 2010

Fingerprint

2,2'-Dipyridyl
Anions
Zinc
Negative ions
zinc
anions
Atoms
Molecules
Carbamates
atoms
molecules
Metals
Geometry
symmetry
geometry
metals

Keywords

  • Data-to-parameter ratio = 18.5.
  • Disorder in main residue
  • Mean σ(C-C) = 0.003 Å
  • R factor = 0.030
  • Single-crystal X-ray study
  • T = 293 K
  • WR factor = 0.091

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

(2,2'-Bipyridine-κ2 N,N')bis-(N-ethyl-N- methyldithiocarbamato-κ2 S,S')zinc(II). / Abdul Ghafar, Noorul Aisyah; Baba, Ibrahim; Mohd. Yamin, Bohari; Ng, Seik Weng.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 2, 2010.

Research output: Contribution to journalArticle

Abdul Ghafar, Noorul Aisyah ; Baba, Ibrahim ; Mohd. Yamin, Bohari ; Ng, Seik Weng. / (2,2'-Bipyridine-κ2 N,N')bis-(N-ethyl-N- methyldithiocarbamato-κ2 S,S')zinc(II). In: Acta Crystallographica Section E: Structure Reports Online. 2010 ; Vol. 66, No. 2.
@article{08f0c4d9f85941ae86c7b026ef5f07be,
title = "(2,2'-Bipyridine-κ2 N,N')bis-(N-ethyl-N- methyldithiocarbamato-κ2 S,S')zinc(II)",
abstract = "The complete molecule of the title compound, [Zn(C4H 8NS2)2(C10H8N 2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C - C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.",
keywords = "Data-to-parameter ratio = 18.5., Disorder in main residue, Mean σ(C-C) = 0.003 {\AA}, R factor = 0.030, Single-crystal X-ray study, T = 293 K, WR factor = 0.091",
author = "{Abdul Ghafar}, {Noorul Aisyah} and Ibrahim Baba and {Mohd. Yamin}, Bohari and Ng, {Seik Weng}",
year = "2010",
doi = "10.1107/S1600536810002606",
language = "English",
volume = "66",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "2",

}

TY - JOUR

T1 - (2,2'-Bipyridine-κ2 N,N')bis-(N-ethyl-N- methyldithiocarbamato-κ2 S,S')zinc(II)

AU - Abdul Ghafar, Noorul Aisyah

AU - Baba, Ibrahim

AU - Mohd. Yamin, Bohari

AU - Ng, Seik Weng

PY - 2010

Y1 - 2010

N2 - The complete molecule of the title compound, [Zn(C4H 8NS2)2(C10H8N 2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C - C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.

AB - The complete molecule of the title compound, [Zn(C4H 8NS2)2(C10H8N 2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C - C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.

KW - Data-to-parameter ratio = 18.5.

KW - Disorder in main residue

KW - Mean σ(C-C) = 0.003 Å

KW - R factor = 0.030

KW - Single-crystal X-ray study

KW - T = 293 K

KW - WR factor = 0.091

UR - http://www.scopus.com/inward/record.url?scp=76749097739&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=76749097739&partnerID=8YFLogxK

U2 - 10.1107/S1600536810002606

DO - 10.1107/S1600536810002606

M3 - Article

C2 - 21579671

AN - SCOPUS:76749097739

VL - 66

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 2

ER -