2-Aminocyclohexan-1-aminium thiocyanate

Research output: Contribution to journalArticle

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Abstract

The title compound, C6H15N2 +·NCS-, was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thiocyanate and cyclohexane-1,2-diamine. The cyclohexane ring adopts a chair conformation. In the crystal, N - H⋯S and N - H⋯N interactions involving the thiocyanate anion and both the amine and the aminium N atoms link the molecules, forming two-dimensional networks parallel to (001).

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number6
DOIs
Publication statusPublished - Jun 2012

Fingerprint

Cyclohexane
cyclohexane
Amines
Anions
Conformations
Atoms
Crystals
ammonium chlorides
Molecules
diamines
seats
amines
Negative ions
anions
rings
crystals
atoms
molecules
interactions
1,2-cyclohexanediamine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

2-Aminocyclohexan-1-aminium thiocyanate. / Salem, Halima F.; Hasbullah, Siti Aishah; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 6, 06.2012.

Research output: Contribution to journalArticle

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AB - The title compound, C6H15N2 +·NCS-, was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thiocyanate and cyclohexane-1,2-diamine. The cyclohexane ring adopts a chair conformation. In the crystal, N - H⋯S and N - H⋯N interactions involving the thiocyanate anion and both the amine and the aminium N atoms link the molecules, forming two-dimensional networks parallel to (001).

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