1,1'-Diphenyl-3,3'-(p-phenylenedicarbonyl)dithiourea

Wong W. Hung, Ibrahim N. Hassan, Bohari Mohd. Yamin, Mohammad Kassim

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The molecule of the title compound, C22H18N 4O2S2, lies across a crystallographic inversion centre. The central benzene ring forms dihedral angles of 29.39 (9) and 79.11 (12)°, respectively, with the thio-urea unit and the terminal phenyl ring. Intra-molecular N -H⋯O hydrogen bonds generate two S(6) ring motifs. In the crystal, molecules are linked into chains along [1 0] by inter-molecular N - H⋯S hydrogen bonds.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number2
DOIs
Publication statusPublished - 2010

Fingerprint

Hydrogen bonds
Molecules
rings
Dihedral angle
Benzene
Urea
hydrogen bonds
ureas
Crystals
dihedral angle
molecules
benzene
inversions
crystals
diphenyl

Keywords

  • Data-to-parameter ratio = 13.3
  • Mean σ(C-C) = 0.004 Å
  • R factor = 0.051
  • Single-crystal X-ray study
  • T = 273 K
  • WR factor = 0.113

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

1,1'-Diphenyl-3,3'-(p-phenylenedicarbonyl)dithiourea. / Hung, Wong W.; Hassan, Ibrahim N.; Mohd. Yamin, Bohari; Kassim, Mohammad.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 66, No. 2, 2010.

Research output: Contribution to journalArticle

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T1 - 1,1'-Diphenyl-3,3'-(p-phenylenedicarbonyl)dithiourea

AU - Hung, Wong W.

AU - Hassan, Ibrahim N.

AU - Mohd. Yamin, Bohari

AU - Kassim, Mohammad

PY - 2010

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N2 - The molecule of the title compound, C22H18N 4O2S2, lies across a crystallographic inversion centre. The central benzene ring forms dihedral angles of 29.39 (9) and 79.11 (12)°, respectively, with the thio-urea unit and the terminal phenyl ring. Intra-molecular N -H⋯O hydrogen bonds generate two S(6) ring motifs. In the crystal, molecules are linked into chains along [1 0] by inter-molecular N - H⋯S hydrogen bonds.

AB - The molecule of the title compound, C22H18N 4O2S2, lies across a crystallographic inversion centre. The central benzene ring forms dihedral angles of 29.39 (9) and 79.11 (12)°, respectively, with the thio-urea unit and the terminal phenyl ring. Intra-molecular N -H⋯O hydrogen bonds generate two S(6) ring motifs. In the crystal, molecules are linked into chains along [1 0] by inter-molecular N - H⋯S hydrogen bonds.

KW - Data-to-parameter ratio = 13.3

KW - Mean σ(C-C) = 0.004 Å

KW - R factor = 0.051

KW - Single-crystal X-ray study

KW - T = 273 K

KW - WR factor = 0.113

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