1-(4-Methylbenzoyl)-3-{2-[3-(4-methylbenzoyl)thioureido]phen-yl}thiourea

Uwaisulqarni M. Osman, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, C 24H 22N 4O 2S 2, the dihedral angles formed by the thioureido groups with the attached benzene ring are 43.81 (13) and 75.25 (13)°. The dihedral angle between the thioureido groups is 85.48 (10)°. The molecule is stabilized by intramolecular N-H⋯S, N- H⋯O and C-H⋯S hydrogen bonds. In the crystal, molecules are linked by intermolecular N- H⋯S hydrogen bonds together with C- H⋯π interactions.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number10
DOIs
Publication statusPublished - Oct 2011

Fingerprint

Thiourea
Thioureas
thioureas
Dihedral angle
dihedral angle
Hydrogen bonds
hydrogen bonds
Molecules
Benzene
molecules
benzene
Crystals
rings
crystals
interactions

Keywords

  • data-to-parameter ratio = 15.2
  • mean σ(C-C) = 0.005 Å
  • R factor = 0.064
  • single-crystal X-ray study
  • T = 298 K
  • wR factor = 0.143

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

1-(4-Methylbenzoyl)-3-{2-[3-(4-methylbenzoyl)thioureido]phen-yl}thiourea. / Osman, Uwaisulqarni M.; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 10, 10.2011.

Research output: Contribution to journalArticle

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N2 - In the title compound, C 24H 22N 4O 2S 2, the dihedral angles formed by the thioureido groups with the attached benzene ring are 43.81 (13) and 75.25 (13)°. The dihedral angle between the thioureido groups is 85.48 (10)°. The molecule is stabilized by intramolecular N-H⋯S, N- H⋯O and C-H⋯S hydrogen bonds. In the crystal, molecules are linked by intermolecular N- H⋯S hydrogen bonds together with C- H⋯π interactions.

AB - In the title compound, C 24H 22N 4O 2S 2, the dihedral angles formed by the thioureido groups with the attached benzene ring are 43.81 (13) and 75.25 (13)°. The dihedral angle between the thioureido groups is 85.48 (10)°. The molecule is stabilized by intramolecular N-H⋯S, N- H⋯O and C-H⋯S hydrogen bonds. In the crystal, molecules are linked by intermolecular N- H⋯S hydrogen bonds together with C- H⋯π interactions.

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KW - wR factor = 0.143

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