1-(4-chlorobutanoyl)-3-(3-chlorophenyl)-thiourea

Hamza M. Abosadiya, Siti Aishah Hasbullah, Bohari Mohd. Yamin, Adibatul H. Fadzil

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The two independent molecules in the asymmetric unit of the title compound, C11H12Cl2N2OS, exhibit different conformations, with the benzene ring and the N2CS thiourea group forming dihedral angles of 87.40 (18) and 69.42 (15)°. An intramolecular N-H⋯O hydrogen bond is present in each molecule. Two further N-H⋯O hydrogen bonds link the independent molecules into a dimer. In the crystal, the dimers are linked by N-H⋯S and C-H⋯S hydrogen bonds, forming chains parallel to the c axis.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number6
DOIs
Publication statusPublished - 2014

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Thiourea
Thioureas
thioureas
Hydrogen bonds
hydrogen bonds
Dimers
Molecules
dimers
molecules
Dihedral angle
Benzene
Conformations
dihedral angle
benzene
Crystals
rings
crystals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

1-(4-chlorobutanoyl)-3-(3-chlorophenyl)-thiourea. / Abosadiya, Hamza M.; Hasbullah, Siti Aishah; Mohd. Yamin, Bohari; Fadzil, Adibatul H.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 70, No. 6, 2014.

Research output: Contribution to journalArticle

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AU - Fadzil, Adibatul H.

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AB - The two independent molecules in the asymmetric unit of the title compound, C11H12Cl2N2OS, exhibit different conformations, with the benzene ring and the N2CS thiourea group forming dihedral angles of 87.40 (18) and 69.42 (15)°. An intramolecular N-H⋯O hydrogen bond is present in each molecule. Two further N-H⋯O hydrogen bonds link the independent molecules into a dimer. In the crystal, the dimers are linked by N-H⋯S and C-H⋯S hydrogen bonds, forming chains parallel to the c axis.

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