1-(4-Chlorobutanoyl)-3-(2-nitrophenyl)thiourea

Nurziana Ngah, Maisara Kadir, Bohari Mohd. Yamin, M. Sukeri M Yusof

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The asymmetric unit of the title compound, C11H 12ClN3O3S, contains two independent molecules with different conformations in which the benzene ring and the thiourea fragment form dihedral angles of 87.28 (12) and 66.44 (10)°. The O atom of the thioamide group is involved in bifurcated N - H⋯O intra- and intramolecular hydrogen bonding; the latter interaction links the independent molecules into a dimer. In the crystal, N - H⋯S interactions link the molecules into chains propagating along the c axis.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number6
DOIs
Publication statusPublished - Jun 2012

Fingerprint

Thiourea
Thioureas
thioureas
Molecules
Thioamides
molecules
Dihedral angle
Benzene
Dimers
Conformations
dihedral angle
Hydrogen bonds
benzene
dimers
fragments
interactions
Atoms
Crystals
rings
hydrogen

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

1-(4-Chlorobutanoyl)-3-(2-nitrophenyl)thiourea. / Ngah, Nurziana; Kadir, Maisara; Mohd. Yamin, Bohari; Yusof, M. Sukeri M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 6, 06.2012.

Research output: Contribution to journalArticle

Ngah, Nurziana ; Kadir, Maisara ; Mohd. Yamin, Bohari ; Yusof, M. Sukeri M. / 1-(4-Chlorobutanoyl)-3-(2-nitrophenyl)thiourea. In: Acta Crystallographica Section E: Structure Reports Online. 2012 ; Vol. 68, No. 6.
@article{89fbd45f17474e50b6ba96127503b960,
title = "1-(4-Chlorobutanoyl)-3-(2-nitrophenyl)thiourea",
abstract = "The asymmetric unit of the title compound, C11H 12ClN3O3S, contains two independent molecules with different conformations in which the benzene ring and the thiourea fragment form dihedral angles of 87.28 (12) and 66.44 (10)°. The O atom of the thioamide group is involved in bifurcated N - H⋯O intra- and intramolecular hydrogen bonding; the latter interaction links the independent molecules into a dimer. In the crystal, N - H⋯S interactions link the molecules into chains propagating along the c axis.",
author = "Nurziana Ngah and Maisara Kadir and {Mohd. Yamin}, Bohari and Yusof, {M. Sukeri M}",
year = "2012",
month = "6",
doi = "10.1107/S160053681202168X",
language = "English",
volume = "68",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "6",

}

TY - JOUR

T1 - 1-(4-Chlorobutanoyl)-3-(2-nitrophenyl)thiourea

AU - Ngah, Nurziana

AU - Kadir, Maisara

AU - Mohd. Yamin, Bohari

AU - Yusof, M. Sukeri M

PY - 2012/6

Y1 - 2012/6

N2 - The asymmetric unit of the title compound, C11H 12ClN3O3S, contains two independent molecules with different conformations in which the benzene ring and the thiourea fragment form dihedral angles of 87.28 (12) and 66.44 (10)°. The O atom of the thioamide group is involved in bifurcated N - H⋯O intra- and intramolecular hydrogen bonding; the latter interaction links the independent molecules into a dimer. In the crystal, N - H⋯S interactions link the molecules into chains propagating along the c axis.

AB - The asymmetric unit of the title compound, C11H 12ClN3O3S, contains two independent molecules with different conformations in which the benzene ring and the thiourea fragment form dihedral angles of 87.28 (12) and 66.44 (10)°. The O atom of the thioamide group is involved in bifurcated N - H⋯O intra- and intramolecular hydrogen bonding; the latter interaction links the independent molecules into a dimer. In the crystal, N - H⋯S interactions link the molecules into chains propagating along the c axis.

UR - http://www.scopus.com/inward/record.url?scp=84862274548&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862274548&partnerID=8YFLogxK

U2 - 10.1107/S160053681202168X

DO - 10.1107/S160053681202168X

M3 - Article

C2 - 22719574

AN - SCOPUS:84862274548

VL - 68

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 6

ER -