1-(4-Chlorobenzoyl)-3-(3-methylpyridin-2-yl)thiourea

M. Sukeri M Yusof, Nurwahyuni A. Mushtari, Maisara A. Kadir, Bohari Mohd. Yamin

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The molecule of the title compound, C 14H 12ClN 3OS, consists of three approximately planar fragments: the central thiourea group, the chlorophenyl group and the picolyl (3-methylpyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea group. The central fragment forms dihedral angles of 33.30 (8) and 76.78 (8)° with the chlorophenyl and picolyl groups, respectively. With respect to the thiourea C - N bonds, the 4-chlorobenzoyl group is positioned trans to the thiono S atoms, whereas the picolyl group lies in a cis position to it. The molecular conformation is stabilized by an intramolecular N - H⋯O hydrogen bond. In the crystal, molecules are linked by intermolecular C - H⋯N hydrogen bonds, forming chains along the a axis.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number9
DOIs
Publication statusPublished - Sep 2011

Fingerprint

Thiourea
Thioureas
thioureas
Hydrogen bonds
Atoms
Molecules
Dihedral angle
Conformations
fragments
hydrogen bonds
Crystals
atoms
dihedral angle
molecules
crystals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

1-(4-Chlorobenzoyl)-3-(3-methylpyridin-2-yl)thiourea. / Yusof, M. Sukeri M; Mushtari, Nurwahyuni A.; Kadir, Maisara A.; Mohd. Yamin, Bohari.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 9, 09.2011.

Research output: Contribution to journalArticle

Yusof, M. Sukeri M ; Mushtari, Nurwahyuni A. ; Kadir, Maisara A. ; Mohd. Yamin, Bohari. / 1-(4-Chlorobenzoyl)-3-(3-methylpyridin-2-yl)thiourea. In: Acta Crystallographica Section E: Structure Reports Online. 2011 ; Vol. 67, No. 9.
@article{eb99f051cb5d4d1388ab372b062fccc7,
title = "1-(4-Chlorobenzoyl)-3-(3-methylpyridin-2-yl)thiourea",
abstract = "The molecule of the title compound, C 14H 12ClN 3OS, consists of three approximately planar fragments: the central thiourea group, the chlorophenyl group and the picolyl (3-methylpyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea group. The central fragment forms dihedral angles of 33.30 (8) and 76.78 (8)° with the chlorophenyl and picolyl groups, respectively. With respect to the thiourea C - N bonds, the 4-chlorobenzoyl group is positioned trans to the thiono S atoms, whereas the picolyl group lies in a cis position to it. The molecular conformation is stabilized by an intramolecular N - H⋯O hydrogen bond. In the crystal, molecules are linked by intermolecular C - H⋯N hydrogen bonds, forming chains along the a axis.",
author = "Yusof, {M. Sukeri M} and Mushtari, {Nurwahyuni A.} and Kadir, {Maisara A.} and {Mohd. Yamin}, Bohari",
year = "2011",
month = "9",
doi = "10.1107/S1600536811032375",
language = "English",
volume = "67",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "9",

}

TY - JOUR

T1 - 1-(4-Chlorobenzoyl)-3-(3-methylpyridin-2-yl)thiourea

AU - Yusof, M. Sukeri M

AU - Mushtari, Nurwahyuni A.

AU - Kadir, Maisara A.

AU - Mohd. Yamin, Bohari

PY - 2011/9

Y1 - 2011/9

N2 - The molecule of the title compound, C 14H 12ClN 3OS, consists of three approximately planar fragments: the central thiourea group, the chlorophenyl group and the picolyl (3-methylpyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea group. The central fragment forms dihedral angles of 33.30 (8) and 76.78 (8)° with the chlorophenyl and picolyl groups, respectively. With respect to the thiourea C - N bonds, the 4-chlorobenzoyl group is positioned trans to the thiono S atoms, whereas the picolyl group lies in a cis position to it. The molecular conformation is stabilized by an intramolecular N - H⋯O hydrogen bond. In the crystal, molecules are linked by intermolecular C - H⋯N hydrogen bonds, forming chains along the a axis.

AB - The molecule of the title compound, C 14H 12ClN 3OS, consists of three approximately planar fragments: the central thiourea group, the chlorophenyl group and the picolyl (3-methylpyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea group. The central fragment forms dihedral angles of 33.30 (8) and 76.78 (8)° with the chlorophenyl and picolyl groups, respectively. With respect to the thiourea C - N bonds, the 4-chlorobenzoyl group is positioned trans to the thiono S atoms, whereas the picolyl group lies in a cis position to it. The molecular conformation is stabilized by an intramolecular N - H⋯O hydrogen bond. In the crystal, molecules are linked by intermolecular C - H⋯N hydrogen bonds, forming chains along the a axis.

UR - http://www.scopus.com/inward/record.url?scp=80052683652&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80052683652&partnerID=8YFLogxK

U2 - 10.1107/S1600536811032375

DO - 10.1107/S1600536811032375

M3 - Article

C2 - 22058973

AN - SCOPUS:80052683652

VL - 67

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 9

ER -