1-(2-Methyl-benzo-yl)-3-m-tolyl-thio-urea

Bohari Mohd. Yamin, S. Yousuf, M. S M Yusof, T. N D T Zakaria

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The molecule of the title compound, C16H16N2OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra-molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio-amide N atom, and between the thio-urea S atom and the H atom of the tolyl group. These hydrogen bonds stabilize the mol-ecule in such a way that the thio-urea group adopts a trans-cis geometry. In the crystal structure, mol-ecules are linked by N - H⋯S inter-molecular hydrogen bonds, forming centrosymmetric dimers.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number7
DOIs
Publication statusPublished - 2008

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Hydrogen
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hydrogen bonds
Amides
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crystal structure
Molecules
Geometry
rings
geometry
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ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

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1-(2-Methyl-benzo-yl)-3-m-tolyl-thio-urea. / Mohd. Yamin, Bohari; Yousuf, S.; Yusof, M. S M; Zakaria, T. N D T.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 64, No. 7, 2008.

Research output: Contribution to journalArticle

Mohd. Yamin, Bohari ; Yousuf, S. ; Yusof, M. S M ; Zakaria, T. N D T. / 1-(2-Methyl-benzo-yl)-3-m-tolyl-thio-urea. In: Acta Crystallographica Section E: Structure Reports Online. 2008 ; Vol. 64, No. 7.
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AB - The molecule of the title compound, C16H16N2OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra-molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio-amide N atom, and between the thio-urea S atom and the H atom of the tolyl group. These hydrogen bonds stabilize the mol-ecule in such a way that the thio-urea group adopts a trans-cis geometry. In the crystal structure, mol-ecules are linked by N - H⋯S inter-molecular hydrogen bonds, forming centrosymmetric dimers.

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